中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Highly selective synthesis of para-cresol by conversion of anisole on ZSM-5 zeolites

文献类型:期刊论文

作者Wang, Kunyuan; Dong, Xinglong; Chen, Zhaoan; He, Yanli; Xu, Yunpeng; Liu, Zhongmin
刊名microporous and mesoporous materials
出版日期2014-02-01
卷号185页码:61-65
关键词Selective catalysis Anisole Para-cresol Para-selectivity ZSM-5
英文摘要a novel route to obtain the high para-selectivity was developed by conversion of anisole on modified zsm-5 in a continuous flowing fixed-bed reactor. it showed that the silylation and steaming treatment were significantly benificial to enhance the para-selectivity. compared with the parent catalysts, the para-selectivity was sharply increased from 18.13% to 69.21% after the second silylation, which was further increased to 80.67% by steaming treatment, the acid sites with different strength of catalysts were studied by nh3-tpd which had an influence on both the para-selectivity and the amount of aromatics in the products. (c) 2013 elsevier inc. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary
研究领域[WOS]chemistry ; science & technology - other topics ; materials science
关键词[WOS]phenol methylation ; chemical-vapor ; p-cresol ; alkylation ; methanol ; catalyst ; hzsm-5 ; surface ; deposition ; mechanism
收录类别SCI
语种英语
WOS记录号WOS:000330930400007
公开日期2016-05-09
源URL[http://cas-ir.dicp.ac.cn/handle/321008/145465]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Wang, Kunyuan,Dong, Xinglong,Chen, Zhaoan,et al. Highly selective synthesis of para-cresol by conversion of anisole on ZSM-5 zeolites[J]. microporous and mesoporous materials,2014,185:61-65.
APA Wang, Kunyuan,Dong, Xinglong,Chen, Zhaoan,He, Yanli,Xu, Yunpeng,&Liu, Zhongmin.(2014).Highly selective synthesis of para-cresol by conversion of anisole on ZSM-5 zeolites.microporous and mesoporous materials,185,61-65.
MLA Wang, Kunyuan,et al."Highly selective synthesis of para-cresol by conversion of anisole on ZSM-5 zeolites".microporous and mesoporous materials 185(2014):61-65.

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来源:大连化学物理研究所

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