Synthesis, structure characterization, and thermochemistry of the coordination compounds of pyridine-2,6-dicarboxylic acid with several metals (Ca and Co)
文献类型：期刊论文
| 作者 | Gao, Z. F.1; Di, Y. Y.1; Tan, Z. C.2; Dou, J. M.1 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2014-02-01 |
| 卷号 | 115期号:2页码:1205-1210 |
| 关键词 | Complexes of pyridine-2 Crystal structure Adiabatic calorimetry Low-temperature heat capacity Thermodynamic function 6-dicarboxylic acid with Ca2+ and Co2+ ions |
| 英文摘要 | two solid state complexes of pyridine-2,6-dicarboxylate with ca2+ and co2+ ions, ca-2(dpc)(2)(h2o)(6)(h2dpc)(2)(s) and co(dpc)(2)center dot co(h2o)(5)center dot 2h(2)o(s), were synthesized. x-ray crystallography was applied to characterize the crystal structures of the two complexes. the molecular and cell stacking structures of the two complexes were shown; the crystal data and refinement details were summarized, and the selected bond lengths and angles of the title complexes were listed. low-temperature heat capacities of the two complexes were measured with an automated adiabatic calorimeter in the temperature ranging from 78 to 380 k. two polynomial equations of experimental molar heat capacities as a function of the temperature were obtained by the least-squares method. the smoothed molar heat capacities and thermodynamic functions of the complexes were calculated based on the fitted polynomial equations. in addition, thermodynamic properties of the two complexes were compared. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | heat-capacity ; thermodynamic properties |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000330729100026 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145480]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Shandong Prov Key Lab Chem Energy Storage & Novel, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Z. F.,Di, Y. Y.,Tan, Z. C.,et al. Synthesis, structure characterization, and thermochemistry of the coordination compounds of pyridine-2,6-dicarboxylic acid with several metals (Ca and Co)[J]. journal of thermal analysis and calorimetry,2014,115(2):1205-1210. |
| APA | Gao, Z. F.,Di, Y. Y.,Tan, Z. C.,&Dou, J. M..(2014).Synthesis, structure characterization, and thermochemistry of the coordination compounds of pyridine-2,6-dicarboxylic acid with several metals (Ca and Co).journal of thermal analysis and calorimetry,115(2),1205-1210. |
| MLA | Gao, Z. F.,et al."Synthesis, structure characterization, and thermochemistry of the coordination compounds of pyridine-2,6-dicarboxylic acid with several metals (Ca and Co)".journal of thermal analysis and calorimetry 115.2(2014):1205-1210. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。