Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargylic Esters with beta-Keto Acids
文献类型：期刊论文
| 作者 | Zhu, Fu-Lin1,2; Wang, Ya-Hui1; Zhang, De-Yang1,2; Hu, Xin-Hu1; Chen, Song1; Hou, Chuan-Jin1,3; Xu, Jie1; Hu, Xiang-Ping1 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2014-10-13 |
| 卷号 | 356期号:14-15页码:3231-3236 |
| 关键词 | asymmetric catalysis copper decarboxylative propargylic alkylation beta-keto acids propargylic esters |
| 英文摘要 | the first copper-catalyzed intermolecular enantioselective decarboxylative propargylic alkylation of propargylic esters with beta-keto acids as surrogates of ketones has been successfully developed by using a ketimine p, n, n-ligand. high yields and excellent enantioselectivities (up to 98% ee) have been achieved under the mild reaction conditions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | substitution-reactions ; conjugate addition ; 1,3-dicarbonyl compounds ; 3-hydroxy oxindoles ; terminal alkynes ; mannich reaction ; ketoacids ; amination ; acetates ; amines |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000342906100043 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145484]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Dalian Polytech Univ, Dalian 116034, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Fu-Lin,Wang, Ya-Hui,Zhang, De-Yang,et al. Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargylic Esters with beta-Keto Acids[J]. advanced synthesis & catalysis,2014,356(14-15):3231-3236. |
| APA | Zhu, Fu-Lin.,Wang, Ya-Hui.,Zhang, De-Yang.,Hu, Xin-Hu.,Chen, Song.,...&Hu, Xiang-Ping.(2014).Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargylic Esters with beta-Keto Acids.advanced synthesis & catalysis,356(14-15),3231-3236. |
| MLA | Zhu, Fu-Lin,et al."Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargylic Esters with beta-Keto Acids".advanced synthesis & catalysis 356.14-15(2014):3231-3236. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。