Selective hydrogenative cleavage of C-C bonds in sorbitol using Ni-Re/C catalyst under nitrogen atmosphere
文献类型：期刊论文
| 作者 | Zhang, Junjie1,2; Lu, Fang1; Yu, Weiqiang1; Chen, Jiazhi1,2; Chen, Shuai1; Gao, Jin1; Xu, Jie1 |
| 刊名 | catalysis today
 |
| 出版日期 | 2014-10-01 |
| 卷号 | 234页码:107-112 |
| 关键词 | Sorbitol Rhenium Nickel Hydrogenative cleavage In situ hydrogen generation |
| 英文摘要 | the use of high pressure fossil derived hydrogen limits the commercial prospects of transforming sorbitol to glycols. ni-re/c catalyst which was developed in this study demonstrated high selectivity toward hydrogenative cleavage of c2-c3 and c3-c4 bonds of sorbitol to produce glycols under 1 mpa nitrogen. acetol which is proposed as important intermediate to explain the reaction mechanism was first detected in the sorbitol conversion reactions. detailed investigations showed that the presence of re could prevent the sintering of ni particles during the reduction process and make the catalyst efficiently generate hydrogen on the active sites to selectively cleave c-c bonds in sorbitol under nitrogen atmosphere. (c) 2014 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | aqueous-phase hydrogenolysis ; ethylene-glycol ; lactic-acid ; glycerol ; conversion ; biomass ; 1,2-propanediol ; ruthenium ; performance ; chemicals |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000339132900013 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145490]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Junjie,Lu, Fang,Yu, Weiqiang,et al. Selective hydrogenative cleavage of C-C bonds in sorbitol using Ni-Re/C catalyst under nitrogen atmosphere[J]. catalysis today,2014,234:107-112. |
| APA | Zhang, Junjie.,Lu, Fang.,Yu, Weiqiang.,Chen, Jiazhi.,Chen, Shuai.,...&Xu, Jie.(2014).Selective hydrogenative cleavage of C-C bonds in sorbitol using Ni-Re/C catalyst under nitrogen atmosphere.catalysis today,234,107-112. |
| MLA | Zhang, Junjie,et al."Selective hydrogenative cleavage of C-C bonds in sorbitol using Ni-Re/C catalyst under nitrogen atmosphere".catalysis today 234(2014):107-112. |
入库方式： OAI收割
来源：大连化学物理研究所
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