N-Heterocyclic Carbene Organocatalytic Reductive beta,beta-Coupling Reactions of Nitroalkenes via Radical Intermediates
文献类型：期刊论文
| 作者 | Du, Yu1; Wang, Yuhuang1; Li, Xin2; Shao, Yaling1; Li, Guohui2; Webster, Richard D.1; Chi, Yonggui Robin1 |
| 刊名 | organic letters
 |
| 出版日期 | 2014-11-07 |
| 卷号 | 16期号:21页码:5678-5681 |
| 英文摘要 | an unprecedented n-heterocyclic carbene catalytic reductive beta,beta-carbon coupling of alpha,beta-nitroalkenes, by using an organic substrate to mimic the one-electron oxidation role of the pyruvate ferredoxin oxidoreductase (pfor) in living systems, has been developed. the reaction goes through a radical anion intermediate generated under a catalytic redox process. for the first time, the presence of radical anion intermediate in nhc organocatalysis is observed and clearly verified. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | pyruvate-ferredoxin oxidoreductase ; intermolecular stetter reaction ; activated double-bonds ; oxidative esterification ; mediated reduction ; stereoselective-synthesis ; catalyzed oxidations ; aliphatic-aldehydes ; benzoin reactions ; esters |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000344635200044 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145494]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Yu,Wang, Yuhuang,Li, Xin,et al. N-Heterocyclic Carbene Organocatalytic Reductive beta,beta-Coupling Reactions of Nitroalkenes via Radical Intermediates[J]. organic letters,2014,16(21):5678-5681. |
| APA | Du, Yu.,Wang, Yuhuang.,Li, Xin.,Shao, Yaling.,Li, Guohui.,...&Chi, Yonggui Robin.(2014).N-Heterocyclic Carbene Organocatalytic Reductive beta,beta-Coupling Reactions of Nitroalkenes via Radical Intermediates.organic letters,16(21),5678-5681. |
| MLA | Du, Yu,et al."N-Heterocyclic Carbene Organocatalytic Reductive beta,beta-Coupling Reactions of Nitroalkenes via Radical Intermediates".organic letters 16.21(2014):5678-5681. |
入库方式： OAI收割
来源：大连化学物理研究所
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