Thermal Methane Activation by La6O10-Cluster Anions
文献类型：期刊论文
| 作者 | Meng, Jing-Heng1,3; Deng, Xiao-Jiao2,3; Li, Zi-Yu1,3; He, Sheng-Gui1; Zheng, Wei-Jun2 |
| 刊名 | chemistry-a european journal
 |
| 出版日期 | 2014-05-05 |
| 卷号 | 20期号:19页码:5580-5583 |
| 关键词 | CH activation density functional calculations mass spectrometry oxide cluster anions reaction mechanisms |
| 英文摘要 | the first example of a metal oxide cluster anion, la6o10- that can activate methane under ambient conditions is reported. this reaction is facilitated by the oxygen-centered radical (o-) and follows the hydrogen atom transfer mechanism. the la6o10- has a high vertical electron detachment energy (vde=4.06ev) and a high symmetry (c-4v). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | oxide cluster cations ; h bond activation ; catalytic-oxidation reactions ; lanthanum oxide ; gas-phase ; ions ; surfaces ; centers ; la2o3 ; generation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000335197000010 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145511]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Meng, Jing-Heng,Deng, Xiao-Jiao,Li, Zi-Yu,et al. Thermal Methane Activation by La6O10-Cluster Anions[J]. chemistry-a european journal,2014,20(19):5580-5583. |
| APA | Meng, Jing-Heng,Deng, Xiao-Jiao,Li, Zi-Yu,He, Sheng-Gui,&Zheng, Wei-Jun.(2014).Thermal Methane Activation by La6O10-Cluster Anions.chemistry-a european journal,20(19),5580-5583. |
| MLA | Meng, Jing-Heng,et al."Thermal Methane Activation by La6O10-Cluster Anions".chemistry-a european journal 20.19(2014):5580-5583. |
入库方式： OAI收割
来源：大连化学物理研究所
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