Lithiated Primary Amine-A New Material for Hydrogen Storage
文献类型：期刊论文
| 作者 | Chen, Juner1,2; Wu, Hui3,4; Wu, Guotao1; Xiong, Zhitao1; Wang, Ruiming1; Fan, Hongjun1; Zhou, Wei3,4; Liu, Bin1; Chua, Yongshen1; Ju, Xiaohua1 |
| 刊名 | chemistry-a european journal
 |
| 出版日期 | 2014-05-26 |
| 卷号 | 20期号:22页码:6632-6635 |
| 关键词 | dehydrogenation hydrogen storage lithiated amines organometallic chemistry -elimination |
| 英文摘要 | a facile method for synthesizing crystalline lithiated amines by ball milling primary amines with lih was developed. the lithiated amines exhibit an unprecedented endothermic dehydrogenation feature in the temperature range of 150-250 degrees c, which shows potential as a new type of hydrogen storage material. structural analysis and mechanistic studies on lithiated ethylenediamine (li(2)eda) indicates that li may mediate the dehydrogenation through an ,-lih elimination mechanism, creating a more energy favorable pathway for the selective h-2 release. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | oxidative dehydrogenation ; pincer complexes ; metal ; catalysts ; lithium ; decomposition ; molybdenum ; activation ; mechanism ; nitriles |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000336002200010 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145514]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA 4.Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA |
| 推荐引用方式 GB/T 7714 | Chen, Juner,Wu, Hui,Wu, Guotao,et al. Lithiated Primary Amine-A New Material for Hydrogen Storage[J]. chemistry-a european journal,2014,20(22):6632-6635. |
| APA | Chen, Juner.,Wu, Hui.,Wu, Guotao.,Xiong, Zhitao.,Wang, Ruiming.,...&Chen, Ping.(2014).Lithiated Primary Amine-A New Material for Hydrogen Storage.chemistry-a european journal,20(22),6632-6635. |
| MLA | Chen, Juner,et al."Lithiated Primary Amine-A New Material for Hydrogen Storage".chemistry-a european journal 20.22(2014):6632-6635. |
入库方式： OAI收割
来源：大连化学物理研究所
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