Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins
文献类型:期刊论文
作者 | Jiang, Miao1,3; Ding, Yunjie1,2; Yan, Li1; Song, Xiangen1; Lin, Ronghe1 |
刊名 | chinese journal of catalysis
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出版日期 | 2014-09-01 |
卷号 | 35期号:9页码:1456-1464 |
关键词 | Triphenylphosphine Knitting aryl network polymer Rhodium Heterogeneous catalyst Hydroformylation of higher olefins |
英文摘要 | rh catalysts supported on knitting aryl network polymers (rh/kaps) were prepared for the hydroformylation of higher olefins. rh catalysts supported on triphenylphosphine-benzene-base polymers (rh/kaps-1) showed higher activity for the higher olefins than rh/sio2 catalysts. fourier transform infrared spectroscopy, thermogravimetry, n-2 adsorption-desorption, x-ray diffraction, transmission electron microscopy, c-13 nmr, and p-31 nmr showed that the rh/icaps-1 catalysts have high thermal stability, high surface area, hierarchical porosity, highly dispersed rh nanoparticles, and in situ formed homogeneous active species during the reaction. (c) 2014, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | modified rh/sio2 catalyst ; carbon-dioxide capture ; heterogeneous catalysts ; microporous polymers ; mesoporous silica ; organic framework ; nanoparticles ; water ; hydrogenation ; propylene |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000341070700005 |
公开日期 | 2016-05-09 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145566] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang, Miao,Ding, Yunjie,Yan, Li,et al. Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins[J]. chinese journal of catalysis,2014,35(9):1456-1464. |
APA | Jiang, Miao,Ding, Yunjie,Yan, Li,Song, Xiangen,&Lin, Ronghe.(2014).Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins.chinese journal of catalysis,35(9),1456-1464. |
MLA | Jiang, Miao,et al."Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins".chinese journal of catalysis 35.9(2014):1456-1464. |
入库方式: OAI收割
来源:大连化学物理研究所
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