Facile preparation of Sn-beta zeolites by post-synthesis (isomorphous substitution) method for isomerization of glucose to fructose
文献类型：期刊论文
| 作者 | Liu, Min1; Jia, Songyan2; Li, Changzeng1; Zhang, Anfeng1; Song, Chunshan1,3,4,5; Guo, Xinwen1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2014-05-01 |
| 卷号 | 35期号:5页码:723-732 |
| 关键词 | Sn-beta Isomorphous substitution Glucose Isomerization Fructose |
| 英文摘要 | sn-beta zeolites were facilely synthesized by a post-synthesis method consisting of two steps, i.e., heteroatom removal and isomorphous substitution by reaction with sncl4. this significantly shortened the sn-beta zeolite preparation time from the previously reported 40 d to less than 1 d. it was shown that sn-beta samples prepared using the post-synthesis method had higher sn contents than that prepared using a hydrothermal method. the as-synthesized sn-beta zeolites were tested in the isomerization of glucose to fructose in aqueous media. the effects of reaction temperature, reaction time, catalyst amount, solvent, and halide additive on the isomerization reaction over sn-al-beta zeolites were studied in detail. under the optimized conditions, the yield of fructose reached a maximum of similar to 43%. the catalysts can be reused without loss of activity after regeneration by calcination. (c) 2014, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | lewis-acid catalyst ; water ; dehydration ; framework ; biomass ; hydroxylation ; hydrocarbons ; conversion ; chemicals ; phenol |
| 收录类别 | SCI ; ISTP |
| 语种 | 英语 |
| WOS记录号 | WOS:000335622300015 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145568]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem Engn, Dept Catalysis Chem & Engn, State Key Lab Fine Chem, Dalian 116012, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 3.Penn State Univ, PSU DUT Joint Ctr Energy Res, EMS Energy Inst, University Pk, PA 16802 USA 4.Penn State Univ, Dept Energy & Mineral Engn, University Pk, PA 16802 USA 5.Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA |
| 推荐引用方式 GB/T 7714 | Liu, Min,Jia, Songyan,Li, Changzeng,et al. Facile preparation of Sn-beta zeolites by post-synthesis (isomorphous substitution) method for isomerization of glucose to fructose[J]. chinese journal of catalysis,2014,35(5):723-732. |
| APA | Liu, Min,Jia, Songyan,Li, Changzeng,Zhang, Anfeng,Song, Chunshan,&Guo, Xinwen.(2014).Facile preparation of Sn-beta zeolites by post-synthesis (isomorphous substitution) method for isomerization of glucose to fructose.chinese journal of catalysis,35(5),723-732. |
| MLA | Liu, Min,et al."Facile preparation of Sn-beta zeolites by post-synthesis (isomorphous substitution) method for isomerization of glucose to fructose".chinese journal of catalysis 35.5(2014):723-732. |
入库方式： OAI收割
来源：大连化学物理研究所
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