Facile synthesis of silver nanoparticles supported on three dimensional graphene oxide/carbon black composite and its application for oxygen reduction reaction
文献类型：期刊论文
| 作者 | Yuan, Lizhi1,2; Jiang, Luhua1; Liu, Jing1,2; Xia, Zhangxun1,2; Wang, Suli1; Sun, Gongquan1 |
| 刊名 | electrochimica acta
 |
| 出版日期 | 2014-07-20 |
| 卷号 | 135页码:168-174 |
| 关键词 | Silver graphene oxide Carbon black Oxygen reduction reaction Electrocatalyst |
| 英文摘要 | a 3d graphene oxide/carbon sphere supported silver composite (ag/go/c) was synthesized using graphene oxide as the reducing agent. the reducing process of ag+ was monitored by the ultra violet-visible (uv-vis) absorption spectrometer and the physical properties of the ag/go/c composite were characterized by fourier transform infrared spectrometer (ftir), transmission electron microscopy (tem), x-ray diffraction (xrd) and x-ray photoelectron spectroscopy (xps). the results demonstrated that the dispersive ag nanoparticles are anchored uniformly on the surface of go sheets with a mean size of about 6.9 nm. with introducing carbon black, the ag nanoparticles aggregated slightly. compared with its counterpart ag/go, the ag/go/c composite showed a significantly enhanced activity towards the oxygen reduction reaction in alkaline media. the enhancement can be ascribed to the 3d composite support, which not only improves the electrical conductivity, but also enforces the mass transport in the catalyst layer facilitating the reactants access to the active sites. moreover, the ag/go/c composite exhibits good tolerance to alcohols, carbonates and tetramethylammonium hydroxide. this work is expected to open a new pathway to use go as a reducing agent to synthesize electrocatalysts without surfactants. crown copyright (c) 2014 published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | electrochemistry |
| 研究领域[WOS] | electrochemistry |
| 关键词[WOS] | metal-free electrocatalysts ; membrane fuel-cells ; alkaline media ; ag nanoparticles ; cathode electrocatalyst ; polycrystalline silver ; catalytic-activity ; carbon ; oxide ; performance |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000339692600023 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145601]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cell & Battery, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, Lizhi,Jiang, Luhua,Liu, Jing,et al. Facile synthesis of silver nanoparticles supported on three dimensional graphene oxide/carbon black composite and its application for oxygen reduction reaction[J]. electrochimica acta,2014,135:168-174. |
| APA | Yuan, Lizhi,Jiang, Luhua,Liu, Jing,Xia, Zhangxun,Wang, Suli,&Sun, Gongquan.(2014).Facile synthesis of silver nanoparticles supported on three dimensional graphene oxide/carbon black composite and its application for oxygen reduction reaction.electrochimica acta,135,168-174. |
| MLA | Yuan, Lizhi,et al."Facile synthesis of silver nanoparticles supported on three dimensional graphene oxide/carbon black composite and its application for oxygen reduction reaction".electrochimica acta 135(2014):168-174. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。