中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystallization behavior of 70GeS(2)-20In(2)S(3)-10CsI chalcohalide glass with silver addition

文献类型:期刊论文

作者Huang, Fei1,2; Xu, Yinsheng1; Chen, Liyan1,2; Nie, Qiuhua1,2; Zhang, Shaoqian3; Dai, Shixun1
刊名journal of thermal analysis and calorimetry
出版日期2014-09-01
卷号117期号:3页码:1271-1276
关键词Chalcogenide glass-ceramics Activation energy Thermal properties Mechanical properties
英文摘要the crystallization behavior of the 70ges(2)-20in(2)s(3)-10csi glass introduced with 2 mol% ag2s system has been studied under non-isothermal condition. the beginning of transmission is shifted toward longer wavelength as a function of annealing temperature. thermal properties were measured by the differential scanning calorimeter. from the heating rate dependence of crystallization temperature, the activation energy (e (c)) for crystallization and the crystallization rate constant (k) were calculated. the k value of 2.44 x 10(9) for the in2s3 phase is about 28 times larger than the second cp, this is why the controllable crystallization to transparent chalcogenide glass-ceramics with sole in2s3 crystallites can be achieved. by heat treatment with various temperatures, the hardness of the glass enhanced from 204 to 230.8 kg mm(-2), while retained the transmittance of the 8-11 mu m.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, analytical ; chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]optical-fibers ; ceramics ; kinetics
收录类别SCI
语种英语
WOS记录号WOS:000340683300031
公开日期2016-05-09
源URL[http://cas-ir.dicp.ac.cn/handle/321008/145615]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Ningbo Univ, Adv Technol Res Inst, Lab Infrared Mat & Devices, Ningbo 315211, Zhejiang, Peoples R China
2.Ningbo Univ, Coll Informat Sci & Engn, Ningbo 315211, Zhejiang, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Chem Laser, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Huang, Fei,Xu, Yinsheng,Chen, Liyan,et al. Crystallization behavior of 70GeS(2)-20In(2)S(3)-10CsI chalcohalide glass with silver addition[J]. journal of thermal analysis and calorimetry,2014,117(3):1271-1276.
APA Huang, Fei,Xu, Yinsheng,Chen, Liyan,Nie, Qiuhua,Zhang, Shaoqian,&Dai, Shixun.(2014).Crystallization behavior of 70GeS(2)-20In(2)S(3)-10CsI chalcohalide glass with silver addition.journal of thermal analysis and calorimetry,117(3),1271-1276.
MLA Huang, Fei,et al."Crystallization behavior of 70GeS(2)-20In(2)S(3)-10CsI chalcohalide glass with silver addition".journal of thermal analysis and calorimetry 117.3(2014):1271-1276.

入库方式: OAI收割

来源:大连化学物理研究所

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