Construction of anti-1,2-diols bearing chiral tertiary alcohol moiety using free hydroxyacetone as aldol donor by imidazole-based prolineamide catalyst
文献类型：期刊论文
| 作者 | Guo, Wengang1,2; Wei, Jianwei1; Liu, Yan1; Li, Can1 |
| 刊名 | tetrahedron
 |
| 出版日期 | 2014-09-16 |
| 卷号 | 70期号:37页码:6561-6568 |
| 关键词 | Imidazole Organocatalyst Hydroxyacetone Asymmetric Aldol reaction |
| 英文摘要 | a direct aldol reaction of free hydroxyacetone and activated ketone has been firstly achieved with a newly developed imidazole-based prolineamide catalyst. the adducts anti-1,2-diols bearing a chiral tertiary alcohol moiety were obtained in high yield (up to 92%) and stereoselectivity (up to 15:1 dr and 90% ee). (c) 2014 published by elsevier ltd. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | asymmetric michael addition ; diels-alder reactions ; alpha-keto esters ; direct syn-aldol ; isotetronic acids ; aqueous-media ; bifunctional organocatalysts ; 1,3-dicarbonyl compounds ; organic-molecules ; methyl ketones |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000340852900022 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145671]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Wengang,Wei, Jianwei,Liu, Yan,et al. Construction of anti-1,2-diols bearing chiral tertiary alcohol moiety using free hydroxyacetone as aldol donor by imidazole-based prolineamide catalyst[J]. tetrahedron,2014,70(37):6561-6568. |
| APA | Guo, Wengang,Wei, Jianwei,Liu, Yan,&Li, Can.(2014).Construction of anti-1,2-diols bearing chiral tertiary alcohol moiety using free hydroxyacetone as aldol donor by imidazole-based prolineamide catalyst.tetrahedron,70(37),6561-6568. |
| MLA | Guo, Wengang,et al."Construction of anti-1,2-diols bearing chiral tertiary alcohol moiety using free hydroxyacetone as aldol donor by imidazole-based prolineamide catalyst".tetrahedron 70.37(2014):6561-6568. |
入库方式： OAI收割
来源：大连化学物理研究所
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