Crystal Structure and Optical Properties of the [Ag62S12(SBut)(32)](2+) Nanocluster with a Complete Face-Centered Cubic Kernel
文献类型：期刊论文
| 作者 | Jin, Shan1,2; Wang, Shuxin1,2; Song, Yongbo1,2; Zhou, Meng3,4; Zhong, Juan; Zhang, Jun1,2,5; Xia, Andong3,4; Pei, Yong5; Chen, Man1,2; Li, Peng1,2 |
| 刊名 | journal of the american chemical society
 |
| 出版日期 | 2014-11-05 |
| 卷号 | 136期号:44页码:15559-15565 |
| 英文摘要 | the crystal structure of the [ag62s12(sbut)32](2+) nanocluster (denoted as nc-i) has been successfully determined, and it shows a complete face-centered-cubic (fcc) ag14 core structure with a ag-48(sbut)32 shell configuration interconnected by 12 sulfide ions, which is similar to the [ag62s13(sbut)32](4+) structure (denoted as nc-ii for short) reported by wang. interestingly, nc-i exhibits prominent differences in the optical properties in comparison with the case of the nc-ii nanocluster. we employed femtosecond transient absorption spectroscopy to further identify the differences between the two nanoclusters. the results show that the quenching of photoluminescence in nc-i in comparison to that of nc-ii is caused by the free valence electrons, which dramatically change the ligand to metal charge transfer (lmct, s 3p -> ag 5s). to get further insight into these, we carried out time-dependent density functional theory (tddft) calculations on the electronic structure and optical absorption spectra of nc-i and nc-ii. these findings offer a new insight into the structure and property evolution of silver cluster materials. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | silver clusters ; gold nanoparticle ; au-25 clusters ; thiolate ; solvation ; interplay ; magnetism ; dynamics ; metal ; state |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000344516600025 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145680]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Anhui Univ, Dept Chem, Hefei 230601, Anhui, Peoples R China 2.Anhui Univ, Ctr Atom Engn Adv Mat, Hefei 230601, Anhui, Peoples R China 3.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 5.Xiangtan Univ, Minist Educ, Dept Chem, Key Lab Environm Friendly Chem & Applicat, Xiangtan 411105, Hunan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin, Shan,Wang, Shuxin,Song, Yongbo,et al. Crystal Structure and Optical Properties of the [Ag62S12(SBut)(32)](2+) Nanocluster with a Complete Face-Centered Cubic Kernel[J]. journal of the american chemical society,2014,136(44):15559-15565. |
| APA | Jin, Shan.,Wang, Shuxin.,Song, Yongbo.,Zhou, Meng.,Zhong, Juan.,...&Zhu, Manzhou.(2014).Crystal Structure and Optical Properties of the [Ag62S12(SBut)(32)](2+) Nanocluster with a Complete Face-Centered Cubic Kernel.journal of the american chemical society,136(44),15559-15565. |
| MLA | Jin, Shan,et al."Crystal Structure and Optical Properties of the [Ag62S12(SBut)(32)](2+) Nanocluster with a Complete Face-Centered Cubic Kernel".journal of the american chemical society 136.44(2014):15559-15565. |
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来源：大连化学物理研究所
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