An Integrated Photoelectrochemical-Chemical Loop for Solar-Driven Overall Splitting of Hydrogen Sulfide**
文献类型：期刊论文
| 作者 | Zong, Xu1,2; Han, Jingfeng3,4,5; Seger, Brian6; Chen, Hongjun1,2; Lu, Gaoqing (Max)1,2; Li, Can3,4; Wang, Lianzhou1,2 |
| 刊名 | angewandte chemie-international edition
 |
| 出版日期 | 2014-04-22 |
| 卷号 | 53期号:17页码:4399-4403 |
| 关键词 | hydrogen generation H2S splitting photoelectrochemistry solar energy sulfur |
| 英文摘要 | abundant and toxic hydrogen sulfide (h2s) from industry and nature has been traditionally considered a liability. however, it represents a potential resource if valuable h-2 and elemental sulfur can be simultaneously extracted through a h2s splitting reaction. herein a photochemical-chemical loop linked by redox couples such as fe2+/fe3+ and i-/i-3(-) for photoelectrochemical h-2 production and h2s chemical absorption redox reactions are reported. using functionalized si as photoelectrodes, h2s was successfully split into elemental sulfur and h-2 with high stability and selectivity under simulated solar light. this new conceptual design will not only provide a possible route for using solar energy to convert h2s into valuable resources, but also sheds light on some challenging photochemical reactions such as ch4 activation and co2 reduction. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | photocatalytic h-2 evolution ; visible-light irradiation ; thermal-decomposition ; energy-conversion ; nonthermal-plasma ; liquid-ammonia ; sulfur ; h2s ; generation ; suspensions |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000334396800023 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145681]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Queensland, Sch Chem Engn, Nanomat Ctr, Brisbane, Qld 4072, Australia 2.Univ Queensland, Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Dalian Lab Clean Energy, Dalian 116023, Peoples R China 5.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 6.Tech Univ Denmark, Dept Phys, CINF, DK-2800 Lyngby, Denmark |
| 推荐引用方式 GB/T 7714 | Zong, Xu,Han, Jingfeng,Seger, Brian,et al. An Integrated Photoelectrochemical-Chemical Loop for Solar-Driven Overall Splitting of Hydrogen Sulfide**[J]. angewandte chemie-international edition,2014,53(17):4399-4403. |
| APA | Zong, Xu.,Han, Jingfeng.,Seger, Brian.,Chen, Hongjun.,Lu, Gaoqing .,...&Wang, Lianzhou.(2014).An Integrated Photoelectrochemical-Chemical Loop for Solar-Driven Overall Splitting of Hydrogen Sulfide**.angewandte chemie-international edition,53(17),4399-4403. |
| MLA | Zong, Xu,et al."An Integrated Photoelectrochemical-Chemical Loop for Solar-Driven Overall Splitting of Hydrogen Sulfide**".angewandte chemie-international edition 53.17(2014):4399-4403. |
入库方式： OAI收割
来源：大连化学物理研究所
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