Rhodium-catalyzed tandem aldol condensation-Robinson annulation between aldehydes and acetone: synthesis of 3-methylcyclohexenones
文献类型：期刊论文
| 作者 | Wang, Fen1; Liu, Yuchen1,2; Qi, Zisong1; Dai, Wei2; Li, Xingwei1 |
| 刊名 | tetrahedron letters
 |
| 出版日期 | 2014-11-19 |
| 卷号 | 55期号:47页码:6399-6402 |
| 关键词 | Rhodium catalysis 3-Methylcyclohexenones Phenol Robinson annulation |
| 英文摘要 | a simple catalytic, redox-neutral access to 3-methylcyclohexenones has been developed via rhodium catalysis in the presence of an amine additive and ag2co3. this process utilized simple aldehydes and acetone as substrates and tolerates a variety of functional groups. disubstituted phenols were isolated in moderate yields when cu(oac)(2) was employed as an oxidant. (c) 2014 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | c-h activation ; alpha,beta-unsaturated ketones ; aerobic dehydrogenation ; cyclohexanones ; aromatization ; arylation ; arenes |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000344825300003 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145689]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Zhejiang Normal Univ, Sch Chem & Biol Sci, Jinhua 321004, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Fen,Liu, Yuchen,Qi, Zisong,et al. Rhodium-catalyzed tandem aldol condensation-Robinson annulation between aldehydes and acetone: synthesis of 3-methylcyclohexenones[J]. tetrahedron letters,2014,55(47):6399-6402. |
| APA | Wang, Fen,Liu, Yuchen,Qi, Zisong,Dai, Wei,&Li, Xingwei.(2014).Rhodium-catalyzed tandem aldol condensation-Robinson annulation between aldehydes and acetone: synthesis of 3-methylcyclohexenones.tetrahedron letters,55(47),6399-6402. |
| MLA | Wang, Fen,et al."Rhodium-catalyzed tandem aldol condensation-Robinson annulation between aldehydes and acetone: synthesis of 3-methylcyclohexenones".tetrahedron letters 55.47(2014):6399-6402. |
入库方式： OAI收割
来源：大连化学物理研究所
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