Photoelectrochemical Properties of CuCrO2: Characterization of Light Absorption and Photocatalytic H-2 Production Performance
文献类型：期刊论文
| 作者 | Ma, Yi1,2; Zhou, Xin2; Ma, Quanbao1; Litke, Anton1; Liu, Peng1; Zhang, Yi1; Li, Can2; Hensen, Emiel J. M.1 |
| 刊名 | catalysis letters
 |
| 出版日期 | 2014-09-01 |
| 卷号 | 144期号:9页码:1487-1493 |
| 关键词 | Photocatalysis Photoelectrochemistry CuCrO2 H-2 production Co-catalysts |
| 英文摘要 | cucro2 delafossite was prepared by the solid-state reaction between cr2o3 and cu2o at high temperature (900-1100 a degrees c). the materials were characterized by xrd, x-ray photoelectron, raman and uv-vis spectroscopy and transmission electron microscopy. the visible light absorption of the p-type semiconductor increased with increasing calcination temperature. first principles density functional theory calculations were used to compute the density of states and distinguish between cr3+ d-d transitions and the charge separation electron transitions, which cannot be distinguished in cucro2 by uv-vis spectroscopy. photocathodes were prepared by depositing the as-prepared cucro2 on an fto substrate by electrophoresis. the resulting cathodic photocurrents under visible light irradiation increased with increasing calcination temperature. cucro2 is a photostable semiconductor unlike cu2o. photocatalytic h-2 production in ethanol/water mixtures shows that the resulting materials are active in water splitting. co-catalysts substantially increase the activity, the most preferred one is pt with an order of magnitude increase in performance. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | total-energy calculations ; augmented-wave method ; hydrogen evolution ; solar-cells ; basis-set ; catalysts ; water ; oxidation ; efficient ; chromite |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000340928800002 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145707]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Yi,Zhou, Xin,Ma, Quanbao,et al. Photoelectrochemical Properties of CuCrO2: Characterization of Light Absorption and Photocatalytic H-2 Production Performance[J]. catalysis letters,2014,144(9):1487-1493. |
| APA | Ma, Yi.,Zhou, Xin.,Ma, Quanbao.,Litke, Anton.,Liu, Peng.,...&Hensen, Emiel J. M..(2014).Photoelectrochemical Properties of CuCrO2: Characterization of Light Absorption and Photocatalytic H-2 Production Performance.catalysis letters,144(9),1487-1493. |
| MLA | Ma, Yi,et al."Photoelectrochemical Properties of CuCrO2: Characterization of Light Absorption and Photocatalytic H-2 Production Performance".catalysis letters 144.9(2014):1487-1493. |
入库方式： OAI收割
来源：大连化学物理研究所
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