Ordered Hierarchically Porous Carbon Codoped with Iron and Nitrogen as Electrocatalyst for the Oxygen Reduction Reaction
文献类型：期刊论文
| 作者 | Deng, Chengwei1,2; Zhong, Hexiang1; Yao, Lan1,2; Liu, Sisi1,2; Xu, Zhuang1; Zhang, Huamin1 |
| 刊名 | chemsuschem
 |
| 出版日期 | 2014-12-01 |
| 卷号 | 7期号:12页码:3435-3441 |
| 关键词 | carbon doping iron nitrogen reduction |
| 英文摘要 | n-doped carbon catalysts have attracted great attention as potential alternatives to expensive pt-based catalysts used in fuel cells. herein, an ordered hierarchically porous carbon codoped with n and fe (fe-nohpc) is prepared by an evaporation-induced self-assembly process followed by carbonization under ammonia. the soft template and fe species promote the formation of the porous structure and facilitate the oxygen reduction reaction (orr). the catalyst possesses an ordered hierarchically porous structure with a large surface area (1172.5 m(2)g(-1)) and pore volume of 1.03 cm(3)g(-1). compared to commercial 20% pt/c, it exhibits better orr catalytic activity and higher stability as well as higher methanol tolerance in an alkaline electrolyte, which demonstrates its potential use in fuel cells as a nonprecious cathode catalyst. the n configuration, fe species, and pore structure of the catalysts are believed to correlate with its high catalytic activity. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | membrane fuel-cells ; mesoporous carbon ; metal-free ; doped graphene ; catalyst ; composite ; fe ; nanoparticles ; melamine ; xerogel |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000345976200034 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145708]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Div Energy Storage, Dalian Natl Lab Clean Energy DNL, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, Chengwei,Zhong, Hexiang,Yao, Lan,et al. Ordered Hierarchically Porous Carbon Codoped with Iron and Nitrogen as Electrocatalyst for the Oxygen Reduction Reaction[J]. chemsuschem,2014,7(12):3435-3441. |
| APA | Deng, Chengwei,Zhong, Hexiang,Yao, Lan,Liu, Sisi,Xu, Zhuang,&Zhang, Huamin.(2014).Ordered Hierarchically Porous Carbon Codoped with Iron and Nitrogen as Electrocatalyst for the Oxygen Reduction Reaction.chemsuschem,7(12),3435-3441. |
| MLA | Deng, Chengwei,et al."Ordered Hierarchically Porous Carbon Codoped with Iron and Nitrogen as Electrocatalyst for the Oxygen Reduction Reaction".chemsuschem 7.12(2014):3435-3441. |
入库方式： OAI收割
来源：大连化学物理研究所
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