The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions
文献类型：期刊论文
| 作者 | Shen, Zheng1,2; Gu, Minyan1; Zhang, Min1; Sang, Wenjing1; Zhou, Xuefei1; Zhang, Yalei1; Jin, Fangmin1 |
| 刊名 | rsc advances
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:29页码:15256-15263 |
| 英文摘要 | recently, formate of possible abiogenic origin has been reported from uncatalyzed transfer hydrogenation of co2 with glycerine under alkaline hydrothermal conditions. however, little is known about the mechanism for production of abiogenic formate from co2 and lactate from glycerine during such processes. herein, we investigated the formation of abiogenic formate from co2, d2o solvent effect, reactor materials effect and h2o molecule catalysis for uncatalyzed transfer hydrogenation of co2 with glycerine under alkaline hydrothermal conditions, and then have proposed and proved the potential reaction mechanism. the present work should help facilitate studies on industrial applications of co2 reduction using abundant alcohol compounds as reducing materials rather than hydrogen, and the development of renewable high-valued chemicals from alternative biomass derivatives and the primary greenhouse gas to fossil fuel. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | high-temperature water ; carbon-dioxide ; formic-acid ; lactic-acid ; supercritical water ; transfer reduction ; organic-compounds ; verley reduction ; acrylic-acid ; catalysis |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000333528900060 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145718]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Tongji Univ, Natl Engn Res Ctr Facil Agr, State Key Lab Pollut Control & Resources Reuse, Key Lab Yangtze River Water Environm,MOE, Shanghai 200092, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, Zheng,Gu, Minyan,Zhang, Min,et al. The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions[J]. rsc advances,2014,4(29):15256-15263. |
| APA | Shen, Zheng.,Gu, Minyan.,Zhang, Min.,Sang, Wenjing.,Zhou, Xuefei.,...&Jin, Fangmin.(2014).The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions.rsc advances,4(29),15256-15263. |
| MLA | Shen, Zheng,et al."The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions".rsc advances 4.29(2014):15256-15263. |
入库方式： OAI收割
来源：大连化学物理研究所
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