A Single 2-(2 '-Hydroxyphenyl)benzothiazole Derivative Can Achieve Pure White-Light Emission
文献类型：期刊论文
| 作者 | Cheng, Jinling1,2; Liu, Di1; Bao, Lijun1; Xu, Kai1; Yang, Yang2; Han, Keli2 |
| 刊名 | chemistry-an asian journal
 |
| 出版日期 | 2014-11-01 |
| 卷号 | 9期号:11页码:3215-3220 |
| 关键词 | charge transfer enols fluorescence hydrogen bonds photophysics |
| 英文摘要 | the synthesis and photophysics of two novel 2-(2'-hydroxyphenyl)-benzothiazole (hbt) derivatives are presented. the electron-withdrawing trifluoromethyl (cf3) group in compound 1 facilitates the deprotonation of the phenolic hydroxy group. well-resolved triple fluorescence from the enol, keto, and phenolic anion, which ranges from 350 to 600 nm, was detected for 1 in ethanol, which marks the first time triple fluorescence from an excited-state intramolecular proton transfer (esipt) molecule has been reported. both triphenylamine and cf3 were introduced into derivative 2. intramolecular charge transfer and the "red-edge effect" resulted in the bathochromic shift of dual fluorescence of 2. triple fluorescence was also observed for 2 in ethanol. in mixed acetonitrile and ethanol, pure white-light emission with cie coordinates of (0.33, 0.33) and a quantum yield of 0.25 was achieved for 2. this work provides a new avenue for the rational design of an esipt molecule to achieve white-light generation under mild conditions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | intramolecular proton-transfer ; emitting devices ; energy-transfer ; transfer esipt ; electroluminescence ; photophysics |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000344332200024 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145730]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem, State Key Lab Fine Chem, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Jinling,Liu, Di,Bao, Lijun,et al. A Single 2-(2 '-Hydroxyphenyl)benzothiazole Derivative Can Achieve Pure White-Light Emission[J]. chemistry-an asian journal,2014,9(11):3215-3220. |
| APA | Cheng, Jinling,Liu, Di,Bao, Lijun,Xu, Kai,Yang, Yang,&Han, Keli.(2014).A Single 2-(2 '-Hydroxyphenyl)benzothiazole Derivative Can Achieve Pure White-Light Emission.chemistry-an asian journal,9(11),3215-3220. |
| MLA | Cheng, Jinling,et al."A Single 2-(2 '-Hydroxyphenyl)benzothiazole Derivative Can Achieve Pure White-Light Emission".chemistry-an asian journal 9.11(2014):3215-3220. |
入库方式： OAI收割
来源：大连化学物理研究所
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