In situ synthesis of Au-Pd bimetallic nanoparticles on amine-functionalized SiO2 for the aqueous-phase hydrodechlorination of chlorobenzene
文献类型：期刊论文
| 作者 | Wang, Xinkui1,2; Liu, Qinggang2; Xiao, Zihui2; Chen, Xiao2; Shi, Chuan2; Tao, Shengyang2; Huang, Yanqiang3; Liang, Changhai2 |
| 刊名 | rsc advances
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:89页码:48254-48259 |
| 英文摘要 | highly dispersed au-pd nanoparticles (nps) with an average size of similar to 3.0 nm were synthesized by in situ reduction of haucl4 and pdcl2 on an amine-functionalized sio2 support. the structural and electronic properties of the au-pd nps were investigated systematically using stem-edx, xrd, uv-vis and xps spectroscopy. it is demonstrated that the composition of the au-pd nps can be tuned by varying the ratio of au- to pd-containing salt in solution. in the aqueous-phase hydrodechlorination of chlorobenzene, the au-pd nps showed a much higher activity and chlorine resistance than the monometallic au and pd counterparts. the effects of base and solvent on the activity over the supported au-pd nps were also investigated. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | metal-organic frameworks ; catalytic hydrodechlorination ; selective oxidation ; supported catalysts ; palladium catalysts ; sol immobilization ; highly efficient ; aryl chlorides ; liquid ; dehalogenation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000343709600035 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145733]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem, State Key Lab Fine Chem, Dalian 116024, Peoples R China 2.Dalian Univ Technol, Sch Chem, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xinkui,Liu, Qinggang,Xiao, Zihui,et al. In situ synthesis of Au-Pd bimetallic nanoparticles on amine-functionalized SiO2 for the aqueous-phase hydrodechlorination of chlorobenzene[J]. rsc advances,2014,4(89):48254-48259. |
| APA | Wang, Xinkui.,Liu, Qinggang.,Xiao, Zihui.,Chen, Xiao.,Shi, Chuan.,...&Liang, Changhai.(2014).In situ synthesis of Au-Pd bimetallic nanoparticles on amine-functionalized SiO2 for the aqueous-phase hydrodechlorination of chlorobenzene.rsc advances,4(89),48254-48259. |
| MLA | Wang, Xinkui,et al."In situ synthesis of Au-Pd bimetallic nanoparticles on amine-functionalized SiO2 for the aqueous-phase hydrodechlorination of chlorobenzene".rsc advances 4.89(2014):48254-48259. |
入库方式： OAI收割
来源：大连化学物理研究所
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