Efficient Co3O4/SiO2 catalyst for the Baeyer-Villiger oxidation of cyclohexanone
文献类型：期刊论文
| 作者 | Zang, Juan1,2; Ding, Yunjie1,3; Pei, Yanpeng1,2; Liu, Jia1,2; Lin, Ronghe1; Yan, Li1; Liu, Tao1; Lu, Yuan1 |
| 刊名 | reaction kinetics mechanisms and catalysis
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 112期号:1页码:159-171 |
| 关键词 | Co3O4/SiO2 Surface oxygen Baeyer-Villiger oxidation Cyclohexanone |
| 英文摘要 | silica-supported tricobalt tetraoxide (co3o4/sio2) catalysts prepared by the impregnation approach with different cobalt loadingswere evaluated in the baeyer-villiger oxidation of cyclohexanone under mukaiyama conditions. among those catalysts with different cobalt contents, 0.5 wt% co3o4/sio2 afforded the best cyclohexanone conversion. also, it provided comparable activity to regular cubic co3o4, which was synthesized by a sophisticated hydrothermal method, under similarly mild conditions. results of various physico-chemical characterizations, including xrd, hrtem, tem, h-2-tpr and o-2-tpd, revealed that highly dispersed co3o4 catalysts showed higher reducibility than those lower dispersed catalysts and possessed more surface oxygen species which seemed reasonable to enhance catalytic activity. the application of co3o4/sio2 catalyst in oxidation of cyclohexanone is promising due to its relatively low-cost, high efficiency and excellent stability. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | molecular-oxygen ; cyclic-ketones ; hydrotalcites ; benzaldehyde ; aldehydes ; beta ; lactones ; zeolites ; shape ; h-2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000339378200012 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145736]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Grad Sch Chinese Acad Sci, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zang, Juan,Ding, Yunjie,Pei, Yanpeng,et al. Efficient Co3O4/SiO2 catalyst for the Baeyer-Villiger oxidation of cyclohexanone[J]. reaction kinetics mechanisms and catalysis,2014,112(1):159-171. |
| APA | Zang, Juan.,Ding, Yunjie.,Pei, Yanpeng.,Liu, Jia.,Lin, Ronghe.,...&Lu, Yuan.(2014).Efficient Co3O4/SiO2 catalyst for the Baeyer-Villiger oxidation of cyclohexanone.reaction kinetics mechanisms and catalysis,112(1),159-171. |
| MLA | Zang, Juan,et al."Efficient Co3O4/SiO2 catalyst for the Baeyer-Villiger oxidation of cyclohexanone".reaction kinetics mechanisms and catalysis 112.1(2014):159-171. |
入库方式： OAI收割
来源：大连化学物理研究所
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