Synthesis, Thermal Behavior, and Dehydrogenation Kinetics Study of Lithiated Ethylenediamine
文献类型：期刊论文
| 作者 | Chen, Juner1,2; Wu, Guotao1; Xiong, Zhitao1; Wu, Hui3,4; Chua, Yong Shen1; Zhou, Wei3,4; Liu, Bin1; Ju, Xiaohua1; Chen, Ping1 |
| 刊名 | chemistry-a european journal
 |
| 出版日期 | 2014-10-13 |
| 卷号 | 20期号:42页码:13636-13643 |
| 关键词 | amines crystallization dehydrogenation ladder polymers lithiation |
| 英文摘要 | the lithiation of ethylenediamine by lih is a stepwise process to form the partially lithiated intermediates lin(h)ch2ch2nh2 and [lin(h)ch2ch2nh2][lin(h)ch2ch2n(h)li](2) prior to the formation of dilithiated ethylenediamine lin(h)ch2ch2n(h)li. a reversible phase transformation between the partial and dilithiated species was observed. one dimensional {linnn} ladders and three-dimensional network structures were found in the crystal structures of lin(h)ch2ch2nh2 and lin(h)ch2ch2n(h)li, respectively. lin(h)ch2ch2n(h)li undergoes dehydrogenation with an activation energy of 181 +/- 8kjmol(-1), whereas the partially lithiated ethylenediamine compounds were polymerized and released ammonia at elevated temperatures. the dynamical dehydrogenation mechanism of the dilithiated ethylenediamine compounds was investigated by using the johnson-mehl-avrami equation. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | amide ladder structures ; mixed aggregate maa ; asymmetric-synthesis ; lithium amides ; hydrogen storage ; allylic amines ; single concept ; ring-stacking ; chemistry ; decomposition |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000342797500025 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145738]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA 4.Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA |
| 推荐引用方式 GB/T 7714 | Chen, Juner,Wu, Guotao,Xiong, Zhitao,et al. Synthesis, Thermal Behavior, and Dehydrogenation Kinetics Study of Lithiated Ethylenediamine[J]. chemistry-a european journal,2014,20(42):13636-13643. |
| APA | Chen, Juner.,Wu, Guotao.,Xiong, Zhitao.,Wu, Hui.,Chua, Yong Shen.,...&Chen, Ping.(2014).Synthesis, Thermal Behavior, and Dehydrogenation Kinetics Study of Lithiated Ethylenediamine.chemistry-a european journal,20(42),13636-13643. |
| MLA | Chen, Juner,et al."Synthesis, Thermal Behavior, and Dehydrogenation Kinetics Study of Lithiated Ethylenediamine".chemistry-a european journal 20.42(2014):13636-13643. |
入库方式： OAI收割
来源：大连化学物理研究所
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