Copper-Mediated Intramolecular Oxidative C-H/C-H Cross-Coupling of alpha-Oxo Ketene N,S-Acetals for Indole Synthesis
文献类型：期刊论文
| 作者 | Huang, Fei1; Wu, Ping1; Wang, Liandi1; Chen, Jiping1; Sun, Chenglin1; Yu, Zhengkun1,2 |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2014-11-07 |
| 卷号 | 79期号:21页码:10553-10560 |
| 英文摘要 | cucl2-mediated intramolecular c-h/c-h cross-dehydrogenative coupling (cdc) of thioalkyl-substituted a-acetyl or alpha-aroyl ketene n,s-acetals afforded 2-thioalkyl indoles. tunable c-s bond transformations of the resultant indoles led to highly functionalized n-heterocyclic compounds. a beta-thioalkyl is necessary to activate the n,s-acetal substrate and enable the cdc reaction to occur, and the relevant mechanism studies revealed that the cdc reaction follows a radical pathway. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | n-aryl enamines ; bond activation ; cyclization ; anilines ; efficient ; functionalization ; heterocycles ; annulation ; catalysis ; oxidant |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000344638200056 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145747]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Fei,Wu, Ping,Wang, Liandi,et al. Copper-Mediated Intramolecular Oxidative C-H/C-H Cross-Coupling of alpha-Oxo Ketene N,S-Acetals for Indole Synthesis[J]. journal of organic chemistry,2014,79(21):10553-10560. |
| APA | Huang, Fei,Wu, Ping,Wang, Liandi,Chen, Jiping,Sun, Chenglin,&Yu, Zhengkun.(2014).Copper-Mediated Intramolecular Oxidative C-H/C-H Cross-Coupling of alpha-Oxo Ketene N,S-Acetals for Indole Synthesis.journal of organic chemistry,79(21),10553-10560. |
| MLA | Huang, Fei,et al."Copper-Mediated Intramolecular Oxidative C-H/C-H Cross-Coupling of alpha-Oxo Ketene N,S-Acetals for Indole Synthesis".journal of organic chemistry 79.21(2014):10553-10560. |
入库方式： OAI收割
来源：大连化学物理研究所
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