Aqueous phase hydrogenation of acetic acid to ethanol over Ir-MoOx/SiO2 catalyst
文献类型:期刊论文
作者 | Wang, Zhiqiang1,2; Li, Guangyi1,3; Liu, Xiaoyan1; Huang, Yanqiang1; Wang, Aiqin1; Chu, Wei2; Wang, Xiaodong1; Li, Ning1 |
刊名 | catalysis communications
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出版日期 | 2014-01-05 |
卷号 | 43页码:38-41 |
关键词 | Aqueous-phase Hydrogenation Acetic acid Ethanol Ir Mo |
英文摘要 | mo modified ir/sio2 (ir-moox/sio2) was firstly used for the aqueous-phase hydrogenation of acetic acid to ethanol and exhibited the best performance among the investigated catalysts. the synergy effect between the closely contacted ir and mo species is responsible for the excellent performance of ir-moox/sio2. ir-moox/sio2 is also effective for the hydrogenation of other biomass derived carboxylic acids. especially when levulinic acid was used as the feedstock, high yields of 2-pentanol (39.0%) and 1,4-pentanediol (42.3%) were obtained simultaneously. to our knowledge, this is the first report about the direct hydrogenation of levulinic acid to 2-pentanol and 1,4-pentanediol over heterogeneous catalyst. (c) 2013 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | succinic acid ; bimetallic catalysts ; carboxylic-acids ; levulinic acid ; biomass ; hydrodeoxygenation ; conversion ; 1,4-butanediol ; selectivity ; chemicals |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000328527000009 |
公开日期 | 2016-05-09 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145748] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Sichuan Univ, Dept Chem Engn, Chengdu 610065, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Zhiqiang,Li, Guangyi,Liu, Xiaoyan,et al. Aqueous phase hydrogenation of acetic acid to ethanol over Ir-MoOx/SiO2 catalyst[J]. catalysis communications,2014,43:38-41. |
APA | Wang, Zhiqiang.,Li, Guangyi.,Liu, Xiaoyan.,Huang, Yanqiang.,Wang, Aiqin.,...&Li, Ning.(2014).Aqueous phase hydrogenation of acetic acid to ethanol over Ir-MoOx/SiO2 catalyst.catalysis communications,43,38-41. |
MLA | Wang, Zhiqiang,et al."Aqueous phase hydrogenation of acetic acid to ethanol over Ir-MoOx/SiO2 catalyst".catalysis communications 43(2014):38-41. |
入库方式: OAI收割
来源:大连化学物理研究所
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