Synthesis of novel perphenylcarbamated beta-cyclodextrin based chiral stationary phases via thiol-ene click chemistry
文献类型：期刊论文
| 作者 | Huang, Guang1,2,3,4; Ou, Junjie1; Zhang, Xiaodan1; Ji, Yongsheng1; Peng, Xiaojun3,4; Zou, Hanfa1 |
| 刊名 | electrophoresis
 |
| 出版日期 | 2014-10-01 |
| 卷号 | 35期号:19页码:2752-2758 |
| 关键词 | Chiral stationary phases beta-Cyclodextrin Enantioseparation HPLC |
| 英文摘要 | novel cyclodextrin (cd) chiral stationary phases (cd-csps) with well-defined structure have been successfully synthesized by immobilization of mono/di(10-undecenoyl)-perphenylaminocarbonyl -cd on the 3-mercaptopropyl functionalized silica gel via thiol-ene click chemistry. the phenyl carbamate groups on the rims of cd extended the cavity of cd-csps, which facilitated the formation of inclusion complex with various types of racemic compounds under rp mode, and also improved the - stacking interaction, dipole-dipole interaction, and hydrogen bonding interaction with racemic compounds under normal phase mode. fifteen racemic compounds were successfully separated on this cd-csp with hplc, and the chromatographic results also demonstrated that thiol-ene click chemistry affords a facile approach for preparation of csps. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
| 类目[WOS] | biochemical research methods ; chemistry, analytical |
| 研究领域[WOS] | biochemistry & molecular biology ; chemistry |
| 关键词[WOS] | performance liquid-chromatography ; multiple urea linkages ; enantiomeric separations ; catalyzed cycloaddition ; facile immobilization ; orthogonal synthesis ; retention behavior ; alpha-cyclodextrin ; gamma-cyclodextrin ; aromatic-compounds |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000342910300007 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145754]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog R&D Ctr, CAS Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China 3.Dalian Univ Technol, State Key Lab Fine Chem, Dalian, Peoples R China 4.Dalian Univ Technol, Dept Analyt Chem, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Guang,Ou, Junjie,Zhang, Xiaodan,et al. Synthesis of novel perphenylcarbamated beta-cyclodextrin based chiral stationary phases via thiol-ene click chemistry[J]. electrophoresis,2014,35(19):2752-2758. |
| APA | Huang, Guang,Ou, Junjie,Zhang, Xiaodan,Ji, Yongsheng,Peng, Xiaojun,&Zou, Hanfa.(2014).Synthesis of novel perphenylcarbamated beta-cyclodextrin based chiral stationary phases via thiol-ene click chemistry.electrophoresis,35(19),2752-2758. |
| MLA | Huang, Guang,et al."Synthesis of novel perphenylcarbamated beta-cyclodextrin based chiral stationary phases via thiol-ene click chemistry".electrophoresis 35.19(2014):2752-2758. |
入库方式： OAI收割
来源：大连化学物理研究所
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