Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates
文献类型：期刊论文
| 作者 | Jin, Weiwei1; Yang, Qin1; Wu, Ping1; Chen, Jiping1; Yu, Zhengkun1,2 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2014-06-16 |
| 卷号 | 356期号:9页码:2097-2102 |
| 关键词 | allyl carbonates allylation C-H activation enones ketene dithioacetals palladium |
| 英文摘要 | the palladium-catalyzed oxidative heck-type allylation of beta,beta-disubstitutedenones, i.e., alpha-oxoketene dithioacetals, was efficiently realized with allyl carbonates, providing a concise route to highly functionalized dienes. the present synthetic methodology utilizes the substrate activation strategy to activate the c-h bond of beta,beta-disubstituted enones by introduction of a 1,2-dithiolane functionality to make the enone substrate highly polarized and thus increase its reactivity, demonstrating rare examples for transition metal-catalyzed allylic substitution of beta,beta-disubstituted enones through a heck-type allylation process. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | oxo ketene dithioacetals ; h bond activation ; efficient synthesis ; simple alkenes ; vinyl ketones ; olefination ; heteroarenes ; derivatives ; zoanthenol ; mechanism |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000337609400020 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145763]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin, Weiwei,Yang, Qin,Wu, Ping,et al. Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates[J]. advanced synthesis & catalysis,2014,356(9):2097-2102. |
| APA | Jin, Weiwei,Yang, Qin,Wu, Ping,Chen, Jiping,&Yu, Zhengkun.(2014).Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates.advanced synthesis & catalysis,356(9),2097-2102. |
| MLA | Jin, Weiwei,et al."Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates".advanced synthesis & catalysis 356.9(2014):2097-2102. |
入库方式： OAI收割
来源：大连化学物理研究所
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