Comparison of cellobiose and glucose transformation to ethylene glycol
文献类型：期刊论文
| 作者 | Zhang, Junying1,2; Yang, Xiaofeng1; Hou, Baolin1; Wang, Aiqin1; Li, Zhenlei1,2; Wang, Hua1; Zhang, Tao1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2014-11-01 |
| 卷号 | 35期号:11页码:1811-1817 |
| 关键词 | Cellobiose Reaction mechanism Glucose Ethylene glycol |
| 英文摘要 | cellobiose was used as a model feedstock to probe the reaction pathways of cellulose to ethylene glycol (eg). its reactivity was compared with that of glucose using a catalyst composed of h2wo4 and ru/c. eg can be produced by both the direct retro-aldol condensation of cellobiose and the retro-aldol condensation of glucose derived from cellobiose hydrolysis. the direct retro-aldol condensation of cellobiose further promoted the hydrolysis of cellobiose. cellobiose has a lower reactivity for retro-aldol condensation than glucose, which decreased the formation rate of glycolaldehyde and made it more matched with the subsequent hydrogenation rate, thus leading to increased yield of eg from cellobiose. (c) 2014, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | tungsten carbide catalysts ; supercritical water ; propylene-glycol ; raney ni ; conversion ; cellulose ; chemicals ; acid ; hydrolysis ; molecules |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000345263700004 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145775]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Junying,Yang, Xiaofeng,Hou, Baolin,et al. Comparison of cellobiose and glucose transformation to ethylene glycol[J]. chinese journal of catalysis,2014,35(11):1811-1817. |
| APA | Zhang, Junying.,Yang, Xiaofeng.,Hou, Baolin.,Wang, Aiqin.,Li, Zhenlei.,...&Zhang, Tao.(2014).Comparison of cellobiose and glucose transformation to ethylene glycol.chinese journal of catalysis,35(11),1811-1817. |
| MLA | Zhang, Junying,et al."Comparison of cellobiose and glucose transformation to ethylene glycol".chinese journal of catalysis 35.11(2014):1811-1817. |
入库方式： OAI收割
来源：大连化学物理研究所
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