中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of 1,10-phenanthroline functionalized periodic mesoporous organosilicas as metal ion-responsive sensors

文献类型:期刊论文

作者Xiao, Bing; Zhao, Jiao; Liu, Xiao; Wang, Peiyuan; Yang, Qihua
刊名microporous and mesoporous materials
出版日期2014-11-15
卷号199页码:1-6
关键词Periodic mesoporous organosilicas (PMOs) 1 Luminescence Sensor 10-Phenanthroline
英文摘要the periodic mesoporous organosilicas with 1,10-phenanthroline (phen) integrated in the framework (phen-pmos) were synthesized by co-condensation of tetramethoxysilane (tmos) and the phenanthroline bridged organosilicas (phen-si) using triblock copolymer p123 as a template in weak acidic medium. the ft-ir, c-13 cp-mas and si-29 mas nmr characterizations confirmed the integration of phenanthroline ligand in material. the phen-pmos have ordered 2-d hexagonal mesostructure though the structural order decreases with the increment in phen content based on xrd and tem characterizations. the hybrid materials exhibited specific surface area of 328-106 m(2)/g and total pore volume of 0.43-0.17 cm(3)/g. these phen-functionalized pmos, with strong blue fluorescent emission originated from phenanthroline group in the framework, have potential application in recognition of different metal ions, with luminescence intensity sensed to the type and concentration of the metal ions. (c) 2014 elsevier inc. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary
研究领域[WOS]chemistry ; science & technology - other topics ; materials science
关键词[WOS]gold nanoparticles ; hybrid materials ; organic groups ; frameworks ; spectroscopy ; mercury(ii) ; sieves ; oxide
收录类别SCI
语种英语
WOS记录号WOS:000342546800001
公开日期2016-05-09
源URL[http://cas-ir.dicp.ac.cn/handle/321008/145820]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Xiao, Bing,Zhao, Jiao,Liu, Xiao,et al. Synthesis of 1,10-phenanthroline functionalized periodic mesoporous organosilicas as metal ion-responsive sensors[J]. microporous and mesoporous materials,2014,199:1-6.
APA Xiao, Bing,Zhao, Jiao,Liu, Xiao,Wang, Peiyuan,&Yang, Qihua.(2014).Synthesis of 1,10-phenanthroline functionalized periodic mesoporous organosilicas as metal ion-responsive sensors.microporous and mesoporous materials,199,1-6.
MLA Xiao, Bing,et al."Synthesis of 1,10-phenanthroline functionalized periodic mesoporous organosilicas as metal ion-responsive sensors".microporous and mesoporous materials 199(2014):1-6.

入库方式: OAI收割

来源:大连化学物理研究所

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