Effects of Mo content on microstructure and corrosion resistance of arc ion plated Ti-Mo-N films on 316L stainless steel as bipolar plates for polymer exchange membrane fuel cells
文献类型：期刊论文
| 作者 | Zhang, Min1,3; Kim, Kwang Ho2; Shao, Zhigang3; Wang, Feifei1; Zhao, Shuang1; Suo, Ni1 |
| 刊名 | journal of power sources
 |
| 出版日期 | 2014-05-01 |
| 卷号 | 253页码:201-204 |
| 关键词 | Ternary film Titanium molybdenum nitride Corrosion resistance Microstructure Bipolar plate |
| 英文摘要 | bipolar plates are one of the most important components in pemfc stack and have multiple functions, such as separators and current collectors, distributing reactions uniformly, and etc. stainless steel is ideal candidate for bipolar plates owing to good thermal and electrical conductivity, good mechanical properties etc. however, stainless steel plate still cannot resist the corrosion of working condition. in this work, ternary ti-mo-n film was fabricated on 316l stainless steel (ss316l) as a surface modification layer to enhance the corrosion resistance. effects of mo content on the microstructure and corrosion resistance of ti-mo-n films are systematically investigated by altering sputtering current of the mo target. xrd results reveal that the preferred orientation changes from [111] to [220] direction as mo content in the film increases. the synthesized ti-mo-n films form a substitutional solid solution of (ti, mo)n where larger mo atoms replace ti in tin crystal lattice. the tin-coated ss316l sample shows the best corrosion resistance. while mo content in the ti-mo-n films increases, the corrosion resistance gradually degrades. compared with the uncoated samples, all the ti-mo-n film coated samples show enhanced corrosion resistance in simulated pemfc working condition. (c) 2013 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | mechanical-properties ; coatings ; titanium ; system |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000331160100026 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145836]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaoning Normal Univ, Sch Phys & Elect Technol, Dalian 116029, Peoples R China 2.Pusan Natl Univ, Natl Core Res Ctr Hybrid Mat Solut, Pusan 735602, South Korea 3.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Fuel Cell Syst & Engn, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Min,Kim, Kwang Ho,Shao, Zhigang,et al. Effects of Mo content on microstructure and corrosion resistance of arc ion plated Ti-Mo-N films on 316L stainless steel as bipolar plates for polymer exchange membrane fuel cells[J]. journal of power sources,2014,253:201-204. |
| APA | Zhang, Min,Kim, Kwang Ho,Shao, Zhigang,Wang, Feifei,Zhao, Shuang,&Suo, Ni.(2014).Effects of Mo content on microstructure and corrosion resistance of arc ion plated Ti-Mo-N films on 316L stainless steel as bipolar plates for polymer exchange membrane fuel cells.journal of power sources,253,201-204. |
| MLA | Zhang, Min,et al."Effects of Mo content on microstructure and corrosion resistance of arc ion plated Ti-Mo-N films on 316L stainless steel as bipolar plates for polymer exchange membrane fuel cells".journal of power sources 253(2014):201-204. |
入库方式： OAI收割
来源：大连化学物理研究所
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