Conversion of carbohydrate biomass to methyl levulinate with Al-2(SO4)(3) as a simple, cheap and efficient catalyst
文献类型：期刊论文
| 作者 | Zhou, Lipeng1; Zou, Haojie1; Nan, Jiaxu1; Wu, Lin1; Yang, Xiaomei1; Su, Yunlai1; Lu, Tianliang2; Xu, Jie2 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2014-05-05 |
| 卷号 | 50页码:13-16 |
| 关键词 | Carbohydrate biomass Glucose Al-2(SO4)(3) Methyl levulinate |
| 英文摘要 | al-2(so4)(3) was developed as a simple and efficient catalyst for the synthesis of methyl levulinate (mle) from carbohydrate biomass including fructose, glucose, mannose, sucrose, cellobiose, starch, and cellulose. the maximum mle yield of 64% from glucose could be obtained at 160 degrees c for 150 min. important roles of al3+ and bronsted acid sites generated by the hydrolysis/methanolysis of al3+ were elucidated. the reaction process was revealed using in situ real-time attenuated total reflection infrared spectroscopy. al-2(so4)(3) can be regenerated easily and reused at least four times without the loss of activity. (c) 2014 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | solid acid catalysts ; ethyl levulinate ; glucose ; cellulose ; isomerization ; fructose ; ethanol ; system ; water ; mechanism |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000336116700004 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145838]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Lipeng,Zou, Haojie,Nan, Jiaxu,et al. Conversion of carbohydrate biomass to methyl levulinate with Al-2(SO4)(3) as a simple, cheap and efficient catalyst[J]. catalysis communications,2014,50:13-16. |
| APA | Zhou, Lipeng.,Zou, Haojie.,Nan, Jiaxu.,Wu, Lin.,Yang, Xiaomei.,...&Xu, Jie.(2014).Conversion of carbohydrate biomass to methyl levulinate with Al-2(SO4)(3) as a simple, cheap and efficient catalyst.catalysis communications,50,13-16. |
| MLA | Zhou, Lipeng,et al."Conversion of carbohydrate biomass to methyl levulinate with Al-2(SO4)(3) as a simple, cheap and efficient catalyst".catalysis communications 50(2014):13-16. |
入库方式： OAI收割
来源：大连化学物理研究所
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