Facile synthesis of POM@MOF embedded in SBA-15 as a steady catalyst for the hydroxylation of benzene
文献类型:期刊论文
作者 | Yang, Hua; Li, Jun; Zhang, Hengyun; Lv, Ying; Gao, Shuang |
刊名 | microporous and mesoporous materials
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出版日期 | 2014-09-01 |
卷号 | 195页码:87-91 |
关键词 | MOF Polyoxometallate Hydroxylation Catalysis Hybrid mesoporous silica |
英文摘要 | we present here a new hybrid material (pom@mof@sba-15, pms) in which metal organic framework (mof) mof-199 encapsulated kegginpolyoxometalate (pom) catalyst (names as pom@mof) was facilely confined in mesoporous sba-15. this mesoporous sba-15 confined mof-199 with encapsulated keggin pom material was exploited to act as a stable heterogeneous poms-based catalyst in a liquid oxidative reaction medium. cycling experiments of the pms catalyst were carried out in the direct synthesis of phenol from benzene and demonstrated unprecedented stability of this novel type pms catalyst. (c) 2014 elsevier inc. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
关键词[WOS] | metal-organic framework ; diblock copolymer ; multilayer films ; oxidation ; silica ; polyoxometalate ; acid ; esterification ; separation ; vanadium |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000337770900012 |
公开日期 | 2016-05-09 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145844] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Hua,Li, Jun,Zhang, Hengyun,et al. Facile synthesis of POM@MOF embedded in SBA-15 as a steady catalyst for the hydroxylation of benzene[J]. microporous and mesoporous materials,2014,195:87-91. |
APA | Yang, Hua,Li, Jun,Zhang, Hengyun,Lv, Ying,&Gao, Shuang.(2014).Facile synthesis of POM@MOF embedded in SBA-15 as a steady catalyst for the hydroxylation of benzene.microporous and mesoporous materials,195,87-91. |
MLA | Yang, Hua,et al."Facile synthesis of POM@MOF embedded in SBA-15 as a steady catalyst for the hydroxylation of benzene".microporous and mesoporous materials 195(2014):87-91. |
入库方式: OAI收割
来源:大连化学物理研究所
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