Enantioselective hydrogenation of alpha,beta-unsaturated carboxylic acid over cinchonidine-modified Pd nanoparticles confined in carbon nanotubes
文献类型：期刊论文
| 作者 | Guan, Zaihong; Lu, Shengmei; Li, Can |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2014-03-01 |
| 卷号 | 311页码:1-5 |
| 关键词 | Carbon nanotubes Asymmetric hydrogenation Heterogeneous Palladium |
| 英文摘要 | we report the enantioselective hydrogenation of alpha,beta-unsaturated acid catalyzed by pd nanoparticles in carbon nanotubes (cnts) taking the advantage of the channels as nanoreactors. the pd nanocatalyst inside the channels of cnts shows higher activity and enantioselectivity than that of pd nanocatalyst outside the channels. as high as 92% enantioselectivity is achieved. the enhanced catalytic performance is attributed to the enrichment of reactant, chiral modifier, and additive in the channels of cnts. this work demonstrates the unique feature of cnts as nanoreactors for asymmetric catalytic reactions. (c) 2013 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | (e)-alpha-phenylcinnamic acid ; asymmetric hydrogenation ; catalytic-properties ; modified pd/tio2 ; fine chemicals ; metal-surfaces ; enhancement ; performance ; dependence ; conversion |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000333489500001 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145846]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guan, Zaihong,Lu, Shengmei,Li, Can. Enantioselective hydrogenation of alpha,beta-unsaturated carboxylic acid over cinchonidine-modified Pd nanoparticles confined in carbon nanotubes[J]. journal of catalysis,2014,311:1-5. |
| APA | Guan, Zaihong,Lu, Shengmei,&Li, Can.(2014).Enantioselective hydrogenation of alpha,beta-unsaturated carboxylic acid over cinchonidine-modified Pd nanoparticles confined in carbon nanotubes.journal of catalysis,311,1-5. |
| MLA | Guan, Zaihong,et al."Enantioselective hydrogenation of alpha,beta-unsaturated carboxylic acid over cinchonidine-modified Pd nanoparticles confined in carbon nanotubes".journal of catalysis 311(2014):1-5. |
入库方式： OAI收割
来源：大连化学物理研究所
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