Highly efficient and reusable Cu-MCM-41 catalyst for the Baeyer-Villiger oxidation of cyclohexanone
文献类型：期刊论文
| 作者 | Zang, Juan1,3; Ding, Yunjie1,2; Yan, Li1; Wang, Tao1; Lu, Yuan1; Gong, Leifeng1 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2014-06-05 |
| 卷号 | 51页码:24-28 |
| 关键词 | Cyclohexanone Baeyer-Villiger Oxidation Benzaldehyde Copper MCM-41 |
| 英文摘要 | a series of cu-mcm-41 with different cu contents were successfully synthesized by the direct hydrothermal (dht) method and evaluated in the baeyer-villiger oxidation of cyclohexanone, using only 2 molar equiv of benzaldehyde as sacrificial agents. high conversion (99.0%) of cyclohexanone and e-caprolactone selectivity (100%) were detected over cu-mcm-41 (23) within 3 h. various physical-chemical characterizations, including bet, xrd, uv-vis and h-2-tpr, revealed that isolated cu2+ species in the mcm-41 framework were responsible for the catalytic activities. this catalyst could be reused for three times without discernible loss in its activity and selectivity. (c) 2014 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | spherical mesoporous silicates ; molecular-oxygen ; selective oxidation ; cyclic-ketones ; copper ; reduction ; mcm-41 ; cu/mcm-41 ; lactones ; hydrotalcite |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000336469200006 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145853]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 3.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zang, Juan,Ding, Yunjie,Yan, Li,et al. Highly efficient and reusable Cu-MCM-41 catalyst for the Baeyer-Villiger oxidation of cyclohexanone[J]. catalysis communications,2014,51:24-28. |
| APA | Zang, Juan,Ding, Yunjie,Yan, Li,Wang, Tao,Lu, Yuan,&Gong, Leifeng.(2014).Highly efficient and reusable Cu-MCM-41 catalyst for the Baeyer-Villiger oxidation of cyclohexanone.catalysis communications,51,24-28. |
| MLA | Zang, Juan,et al."Highly efficient and reusable Cu-MCM-41 catalyst for the Baeyer-Villiger oxidation of cyclohexanone".catalysis communications 51(2014):24-28. |
入库方式： OAI收割
来源：大连化学物理研究所
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