中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Highly efficient and reusable Cu-MCM-41 catalyst for the Baeyer-Villiger oxidation of cyclohexanone

文献类型:期刊论文

作者Zang, Juan1,3; Ding, Yunjie1,2; Yan, Li1; Wang, Tao1; Lu, Yuan1; Gong, Leifeng1
刊名catalysis communications
出版日期2014-06-05
卷号51页码:24-28
关键词Cyclohexanone Baeyer-Villiger Oxidation Benzaldehyde Copper MCM-41
英文摘要a series of cu-mcm-41 with different cu contents were successfully synthesized by the direct hydrothermal (dht) method and evaluated in the baeyer-villiger oxidation of cyclohexanone, using only 2 molar equiv of benzaldehyde as sacrificial agents. high conversion (99.0%) of cyclohexanone and e-caprolactone selectivity (100%) were detected over cu-mcm-41 (23) within 3 h. various physical-chemical characterizations, including bet, xrd, uv-vis and h-2-tpr, revealed that isolated cu2+ species in the mcm-41 framework were responsible for the catalytic activities. this catalyst could be reused for three times without discernible loss in its activity and selectivity. (c) 2014 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]spherical mesoporous silicates ; molecular-oxygen ; selective oxidation ; cyclic-ketones ; copper ; reduction ; mcm-41 ; cu/mcm-41 ; lactones ; hydrotalcite
收录类别SCI
语种英语
WOS记录号WOS:000336469200006
公开日期2016-05-09
源URL[http://cas-ir.dicp.ac.cn/handle/321008/145853]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
3.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Zang, Juan,Ding, Yunjie,Yan, Li,et al. Highly efficient and reusable Cu-MCM-41 catalyst for the Baeyer-Villiger oxidation of cyclohexanone[J]. catalysis communications,2014,51:24-28.
APA Zang, Juan,Ding, Yunjie,Yan, Li,Wang, Tao,Lu, Yuan,&Gong, Leifeng.(2014).Highly efficient and reusable Cu-MCM-41 catalyst for the Baeyer-Villiger oxidation of cyclohexanone.catalysis communications,51,24-28.
MLA Zang, Juan,et al."Highly efficient and reusable Cu-MCM-41 catalyst for the Baeyer-Villiger oxidation of cyclohexanone".catalysis communications 51(2014):24-28.

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来源:大连化学物理研究所

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