Cross linked poly(vinylbenzyl chloride) with a macromolecular crosslinker for anion exchange membrane fuel cells
文献类型：期刊论文
| 作者 | Lu, Wangting1,2; Shao, Zhi-Gang1; Zhang, Geng1,2; Zhao, Yun1; Yi, Baolian1 |
| 刊名 | journal of power sources
 |
| 出版日期 | 2014-02-15 |
| 卷号 | 248页码:905-914 |
| 关键词 | Poly(vinylbenzyl chloride) Anion exchange membrane Crosslinking Macromolecular crosslinker Fuel cell |
| 英文摘要 | a new material based on crosslinked poly(vinylbenzyl chloride) (pvbc) with a macromolecular crosslinker is synthesized and employed as the membrane for anion exchange membrane fuel cells (aemfcs). pvbc is used as the hydroxide conducting polymers, while poly(vinyl acetal) (pvac) containing dimethylamino groups plays the role as macromolecular crosslinker and the supporting matrix simultaneously. fourier transform infrared (ft-ir) absorption spectra and x-ray photoelectron (xps) spectra prove successful crosslinking between pvbc and pvac. the crosslinked membrane shows hydroxide conductivity larger than 0.01 s cm(-1) at room temperature, and the swelling by water at elevated temperature is suppressed. the h-2/o-2 aemfc using the crosslinked membrane shows a peak power density (p-max) of 124.7 mw cm(-2) at 40 degrees c, and the decrease of the open circuit voltage (ocv) of the fuel cell is negligible under continuous ocv conditions for 120 h. all the results indicate that the crosslinking with a macromolecular crosslinker may be a promising strategy to fabricate anion exchange membrane for the application in the aemfcs. (c) 2013 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | poly(arylene ether sulfone) ; polymer ; electrolyte ; durability ; stability |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000330551000113 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145863]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Syst & Engn Grp, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Wangting,Shao, Zhi-Gang,Zhang, Geng,et al. Cross linked poly(vinylbenzyl chloride) with a macromolecular crosslinker for anion exchange membrane fuel cells[J]. journal of power sources,2014,248:905-914. |
| APA | Lu, Wangting,Shao, Zhi-Gang,Zhang, Geng,Zhao, Yun,&Yi, Baolian.(2014).Cross linked poly(vinylbenzyl chloride) with a macromolecular crosslinker for anion exchange membrane fuel cells.journal of power sources,248,905-914. |
| MLA | Lu, Wangting,et al."Cross linked poly(vinylbenzyl chloride) with a macromolecular crosslinker for anion exchange membrane fuel cells".journal of power sources 248(2014):905-914. |
入库方式： OAI收割
来源：大连化学物理研究所
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