Efficient aerobic oxidation of biomass-derived 5-hydroxymethylfurfural to 2,5-diformylfuran catalyzed by magnetic nanoparticle supported manganese oxide
文献类型：期刊论文
| 作者 | Liu, Bing1,2; Zhang, Zehui1,2; Lv, Kangle1,2; Deng, Kejian1,2; Duan, Hongmin3 |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2014-02-22 |
| 卷号 | 472页码:64-71 |
| 关键词 | Biomass 2 Aerobic oxidation 5-Hydroxymethylfurfural Manganese oxide Magnetic nanoparticles 5-Diformylfuran |
| 英文摘要 | magnetic fe3o4 supported mn3o4 nanoparticles (fe3o4/mn3o4) were prepared by the solvent thermal method, and its structure was characterized by xrd, xi's, tem, and ft-ir technologies. the resulting fe3o4/mn3o4 nanoparticles could be used as an excellent heterogeneous catalyst for the aerobic oxidation of the biomass-derived model molecule 5-hydroxymethylfurfural into 2,5-diformylfuran (dff) under benign reaction conditions. some important reaction parameters such as reaction temperature, catalyst amount, solvent, oxidant, and oxygen pressure were explored and high dff yield of 82.1% with hmf conversion of 100% were obtained in dmf under optimal reaction conditions. more importantly, the catalyst could be readily separated from the reaction mixture by a permanent magnet, and recycled up to 6 times without the significant loss of its catalytic activity. (c) 2013 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | pulsed-laser ablation ; heterogeneous catalyst ; selective oxidation ; ionic liquids ; conversion ; acid ; derivatives ; cellulose ; fructose ; hemicellulose |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000333856200008 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145875]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.South Cent Univ Nationalities, Dept Chem, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Peoples R China 2.South Cent Univ Nationalities, Minist Educ, Wuhan 430074, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Bing,Zhang, Zehui,Lv, Kangle,et al. Efficient aerobic oxidation of biomass-derived 5-hydroxymethylfurfural to 2,5-diformylfuran catalyzed by magnetic nanoparticle supported manganese oxide[J]. applied catalysis a-general,2014,472:64-71. |
| APA | Liu, Bing,Zhang, Zehui,Lv, Kangle,Deng, Kejian,&Duan, Hongmin.(2014).Efficient aerobic oxidation of biomass-derived 5-hydroxymethylfurfural to 2,5-diformylfuran catalyzed by magnetic nanoparticle supported manganese oxide.applied catalysis a-general,472,64-71. |
| MLA | Liu, Bing,et al."Efficient aerobic oxidation of biomass-derived 5-hydroxymethylfurfural to 2,5-diformylfuran catalyzed by magnetic nanoparticle supported manganese oxide".applied catalysis a-general 472(2014):64-71. |
入库方式： OAI收割
来源：大连化学物理研究所
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