State-to-state dynamics of the H*(n) plus HD -> D*(n ') + H-2 reactive scattering
文献类型：期刊论文
| 作者 | Yu, Shengrui; Su, Shu; Dai, Dongxu; Yuan, Kaijun; Yang, Xueming |
| 刊名 | journal of chemical physics
 |
| 出版日期 | 2014-01-21 |
| 卷号 | 140期号:3 |
| 英文摘要 | the state-to-state dynamics of the h*(n) + hd -> d*(n') + h-2 reactive scattering at the collision energy of 0.5 ev have been carried out for the first time by using h-atom rydberg tagging time-of-flight technique. experimental results show that the angular distribution of the total h-2 products presents clearly forward-backward asymmetric, which considerably differs from that of the corresponding h+ + hd -> d+ + h-2 reaction predicted by previously theoretical calculations. such disagreement between these two processes suggests that the fermi independent-collider model is also not valid in describing the dynamics of isotopic variants of the h* + h-2 reaction. the rotational state distribution of the h-2 products demonstrates a saw-toothed distribution with odd-j' > even-j'. this interesting observation is strongly influenced by nuclear spin statistics. (c) 2014 aip publishing llc. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | potential-energy surfaces ; differential cross-sections ; reactive scattering ; h-3(+) ; hydrogen ; system ; d+ ; h+ ; collisions ; atom |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000330614400028 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145877]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Shengrui,Su, Shu,Dai, Dongxu,et al. State-to-state dynamics of the H*(n) plus HD -> D*(n ') + H-2 reactive scattering[J]. journal of chemical physics,2014,140(3). |
| APA | Yu, Shengrui,Su, Shu,Dai, Dongxu,Yuan, Kaijun,&Yang, Xueming.(2014).State-to-state dynamics of the H*(n) plus HD -> D*(n ') + H-2 reactive scattering.journal of chemical physics,140(3). |
| MLA | Yu, Shengrui,et al."State-to-state dynamics of the H*(n) plus HD -> D*(n ') + H-2 reactive scattering".journal of chemical physics 140.3(2014). |
入库方式： OAI收割
来源：大连化学物理研究所
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