An amphiphilic organic catalyst for the direct asymmetric Michael addition of cycloketone to nitroolefins in water
文献类型：期刊论文
| 作者 | Wei, Jianwei1,2; Guo, Wengang2; Zhang, Boyu2; Liu, Yan2; Du, Xin1; Li, Can2 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2014-07-01 |
| 卷号 | 35期号:7页码:1008-1011 |
| 关键词 | Asymmetric catalysis Emulsion Organocatalysis Michael addition |
| 英文摘要 | a series of amphiphilic proline-derived mercapto imidazole organic catalysts were synthesized and shown to be very effective with an acid cocatalyst for the asymmetric michael addition reaction of ketones to nitroolefins with high diastereoselectivity (up to 99:1) and execellent enantioselectivity (up to 96%) using water as solvent. (c) 2014, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | emulsion droplets ; aldol reactions ; nitro olefins ; ketones ; aldehydes ; organocatalysts ; nitrostyrene ; proline ; acids |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000338913700004 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145878]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Dept Chem, Dalian 116024, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, Jianwei,Guo, Wengang,Zhang, Boyu,et al. An amphiphilic organic catalyst for the direct asymmetric Michael addition of cycloketone to nitroolefins in water[J]. chinese journal of catalysis,2014,35(7):1008-1011. |
| APA | Wei, Jianwei,Guo, Wengang,Zhang, Boyu,Liu, Yan,Du, Xin,&Li, Can.(2014).An amphiphilic organic catalyst for the direct asymmetric Michael addition of cycloketone to nitroolefins in water.chinese journal of catalysis,35(7),1008-1011. |
| MLA | Wei, Jianwei,et al."An amphiphilic organic catalyst for the direct asymmetric Michael addition of cycloketone to nitroolefins in water".chinese journal of catalysis 35.7(2014):1008-1011. |
入库方式： OAI收割
来源：大连化学物理研究所
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