Hydrogenation/Hydrolytic Ring Opening of 5-HMF by Cp*-Iridium(III) Half-Sandwich Complexes for Bioketones Synthesis
文献类型：期刊论文
| 作者 | Xu, Zhanwei; Yan, Peifang; Xu, Wenjuan; Liu, Xiumei; Xia, Zhi; Chung, Benjamin; Jia, Songyan; Zhang, Z. Conrad |
| 刊名 | acs catalysis
 |
| 出版日期 | 2015-02-01 |
| 卷号 | 5期号:2页码:788-792 |
| 关键词 | homogeneous catalysis hydrogenation iridium catalyst 5-HMF ketones |
| 英文摘要 | a new method for one-step synthesis of ketones from biobased 5-hydroxymethylfurfural (5-hmf) and its derivatives is reported. bipyridine coordinated cp*-iridium(iii) complexes (cp*, 1,2,3,4,5-pentamethylcyclopenta-1,3-diene) exhibit highly efficient catalytic performance for hydrogenation/hydrolytic ring opening of 5-hmf and derivatives to produce ketones. the catalytic mechanism is proposed to proceed via carbonyl hydrogenation, hydroxyl group promoted and directed hydrolytic furan ring opening, followed by hydrogenation of a,fi-unsaturated carbonyl compound based on the experimental and independent events' statistical calculation results. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | catalytic conversion ; renewable resources ; iridium complexes ; levulinic acid ; biomass ; fructose ; hydrodeoxygenation ; hydrogenolysis ; decomposition ; reduction |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000349275300034 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145939]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Zhanwei,Yan, Peifang,Xu, Wenjuan,et al. Hydrogenation/Hydrolytic Ring Opening of 5-HMF by Cp*-Iridium(III) Half-Sandwich Complexes for Bioketones Synthesis[J]. acs catalysis,2015,5(2):788-792. |
| APA | Xu, Zhanwei.,Yan, Peifang.,Xu, Wenjuan.,Liu, Xiumei.,Xia, Zhi.,...&Zhang, Z. Conrad.(2015).Hydrogenation/Hydrolytic Ring Opening of 5-HMF by Cp*-Iridium(III) Half-Sandwich Complexes for Bioketones Synthesis.acs catalysis,5(2),788-792. |
| MLA | Xu, Zhanwei,et al."Hydrogenation/Hydrolytic Ring Opening of 5-HMF by Cp*-Iridium(III) Half-Sandwich Complexes for Bioketones Synthesis".acs catalysis 5.2(2015):788-792. |
入库方式： OAI收割
来源：大连化学物理研究所
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