Fischer-Tropsch synthesis: Characterizing and reaction testing of Co2C/SiO2 and Co2C/Al2O3 catalysts
文献类型：期刊论文
| 作者 | Pei, Yanpeng1,3; Ding, Yunjie1,2; Zang, Juan1,3; Song, Xiangen1,3; Dong, Wenda1,3; Zhu, Hejun1; Wang, Tao1; Chen, Weimiao1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2015-02-01 |
| 卷号 | 36期号:2页码:252-259 |
| 关键词 | Supported cobalt carbide Fischer-Tropsch synthesis Alcohols Surface sites |
| 英文摘要 | sio2- and al2o3-supported co2c catalysts were prepared by carburizing supported co precursors with co. the catalysts were characterized by n-2 physisorption, x-ray diffraction and h-2 temperature-programmed reduction techniques, and evaluated by the fischer-tropsch (f-t) reaction. the results showed that sio2- and al2o3-supported co2c catalysts could be successfully obtained but sufficient carburization time was required. all of the as-prepared supported co2c catalysts exhibited activity and selectivity towards alcohols. it is considered that surface metallic co species contributed to the activity, surface co2c species were responsible for the formation of alcohols, and bulk co2c species were inert during the f-t reaction. (c) 2015, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | density-functional theory ; linear alpha-alcohols ; cobalt carbide co2c ; co/ac catalysts ; surface ; hydrogenation ; deactivation ; performance ; syngas ; la2o3 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000349202600018 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145954]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pei, Yanpeng,Ding, Yunjie,Zang, Juan,et al. Fischer-Tropsch synthesis: Characterizing and reaction testing of Co2C/SiO2 and Co2C/Al2O3 catalysts[J]. chinese journal of catalysis,2015,36(2):252-259. |
| APA | Pei, Yanpeng.,Ding, Yunjie.,Zang, Juan.,Song, Xiangen.,Dong, Wenda.,...&Chen, Weimiao.(2015).Fischer-Tropsch synthesis: Characterizing and reaction testing of Co2C/SiO2 and Co2C/Al2O3 catalysts.chinese journal of catalysis,36(2),252-259. |
| MLA | Pei, Yanpeng,et al."Fischer-Tropsch synthesis: Characterizing and reaction testing of Co2C/SiO2 and Co2C/Al2O3 catalysts".chinese journal of catalysis 36.2(2015):252-259. |
入库方式： OAI收割
来源：大连化学物理研究所
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