Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors
文献类型：期刊论文
| 作者 | Peng, Juan1,2; Wang, Xuefeng1; Zhang, Xiaoming1,2; Bai, Shiyang1; Zhao, Yaopeng1; Li, Can1; Yang, Qihua1 |
| 刊名 | catalysis science & technology
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:2页码:666-672 |
| 英文摘要 | the noyori catalyst rucl2(r-binap)(dmf)(n) has been successfully encapsulated in c-fdu-12 by using the active chlorosilane ph2cl2si as the silylating agent. p-31-nmr results show that there is no strong interaction between the molecular catalyst and the solid support, thus the encapsulated molecular catalyst could move freely in the nanoreactor during the catalytic process. the solid catalyst exhibits high activity and enantioselectivity for the asymmetric hydrogenation of a series of beta-keto esters due to the preserved intrinsic properties of rucl2(r-binap)(dmf)(n) encapsulated in the nanoreactor. the solid catalyst could be recycled by simple filtration and be reused at least four times. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | chiral catalysts ; aromatic ketones ; magnetite nanoparticles ; kinetic resolution ; mesoporous silica ; hybrid solids ; zeolite-y ; binap ; ru ; complex |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000348937900005 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145956]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, Juan,Wang, Xuefeng,Zhang, Xiaoming,et al. Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors[J]. catalysis science & technology,2015,5(2):666-672. |
| APA | Peng, Juan.,Wang, Xuefeng.,Zhang, Xiaoming.,Bai, Shiyang.,Zhao, Yaopeng.,...&Yang, Qihua.(2015).Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors.catalysis science & technology,5(2),666-672. |
| MLA | Peng, Juan,et al."Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors".catalysis science & technology 5.2(2015):666-672. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。