中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors

文献类型:期刊论文

作者Peng, Juan1,2; Wang, Xuefeng1; Zhang, Xiaoming1,2; Bai, Shiyang1; Zhao, Yaopeng1; Li, Can1; Yang, Qihua1
刊名catalysis science & technology
出版日期2015
卷号5期号:2页码:666-672
英文摘要the noyori catalyst rucl2(r-binap)(dmf)(n) has been successfully encapsulated in c-fdu-12 by using the active chlorosilane ph2cl2si as the silylating agent. p-31-nmr results show that there is no strong interaction between the molecular catalyst and the solid support, thus the encapsulated molecular catalyst could move freely in the nanoreactor during the catalytic process. the solid catalyst exhibits high activity and enantioselectivity for the asymmetric hydrogenation of a series of beta-keto esters due to the preserved intrinsic properties of rucl2(r-binap)(dmf)(n) encapsulated in the nanoreactor. the solid catalyst could be recycled by simple filtration and be reused at least four times.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]chiral catalysts ; aromatic ketones ; magnetite nanoparticles ; kinetic resolution ; mesoporous silica ; hybrid solids ; zeolite-y ; binap ; ru ; complex
收录类别SCI
语种英语
WOS记录号WOS:000348937900005
公开日期2016-05-09
源URL[http://cas-ir.dicp.ac.cn/handle/321008/145956]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Peng, Juan,Wang, Xuefeng,Zhang, Xiaoming,et al. Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors[J]. catalysis science & technology,2015,5(2):666-672.
APA Peng, Juan.,Wang, Xuefeng.,Zhang, Xiaoming.,Bai, Shiyang.,Zhao, Yaopeng.,...&Yang, Qihua.(2015).Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors.catalysis science & technology,5(2),666-672.
MLA Peng, Juan,et al."Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors".catalysis science & technology 5.2(2015):666-672.

入库方式: OAI收割

来源:大连化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。