Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds
文献类型：期刊论文
| 作者 | Jiang, Quanbin1; Guo, Tenglong1; Yu, Zhengkun1,2 |
| 刊名 | chemcatchem
 |
| 出版日期 | 2015-02-01 |
| 卷号 | 7期号:4页码:660-665 |
| 关键词 | asymmetric catalysis copper enones homogeneous catalysis ketones |
| 英文摘要 | the cu-catalyzed, one-pot tandem (asymmetric) borylation of -chloroalkyl aryl ketones via the insitu generated acyclic enones with bis(pinacolato)diboron was achieved efficiently to reach up to 97% yield and 99% enantioselectivity for the formal sp(3) ccl borylation products. the present methodology provides an efficient alternative route to (chiral) alkylboron compounds. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | alpha,beta-unsaturated carbonyl-compounds ; boron conjugate additions ; enantioselective synthesis ; saturated ketones ; bond formation ; boration ; esters ; alcohols ; oxidation ; enones |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000349917900017 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145962]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Quanbin,Guo, Tenglong,Yu, Zhengkun. Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds[J]. chemcatchem,2015,7(4):660-665. |
| APA | Jiang, Quanbin,Guo, Tenglong,&Yu, Zhengkun.(2015).Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds.chemcatchem,7(4),660-665. |
| MLA | Jiang, Quanbin,et al."Copper-Catalyzed Tandem Asymmetric Borylation of beta-Chloroalkyl Aryl Ketones and Related Compounds".chemcatchem 7.4(2015):660-665. |
入库方式： OAI收割
来源：大连化学物理研究所
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