Heterogeneous asymmetric hydrogenation over chiral molecule-modified metal particles
文献类型：期刊论文
| 作者 | Zhan, Ensheng; Chen, Chunhui; Li, Yong; Shen, Wenjie |
| 刊名 | catalysis science & technology
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:2页码:650-659 |
| 英文摘要 | heterogeneous asymmetric hydrogenation of c=o and c=c bonds over chiral molecule-modified metal particles represents an important route for the production of chiral compounds. in this mini review, we first briefly introduced the background of heterogeneous asymmetric hydrogenation and the remaining challenges in this field. then, we highlighted recent important progress in the understanding of the reaction mechanism in terms of the acid-base properties of supports and the effects of the size/shape of metal particles. finally, we summarized the possible models proposed for the substrate-modifier adsorption and their interaction in asymmetric hydrogenation reactions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | cinchonidine-modified palladium ; alpha,beta-unsaturated carboxylic-acids ; enantio-selective hydrogenation ; modified pd catalysts ; modified pd/al2o3 catalysts ; modified pd/tio2 catalysts ; bed reactor system ; enantioselective hydrogenation ; (e)-alpha-phenylcinnamic acid ; activated ketones |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000348937900003 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145997]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhan, Ensheng,Chen, Chunhui,Li, Yong,et al. Heterogeneous asymmetric hydrogenation over chiral molecule-modified metal particles[J]. catalysis science & technology,2015,5(2):650-659. |
| APA | Zhan, Ensheng,Chen, Chunhui,Li, Yong,&Shen, Wenjie.(2015).Heterogeneous asymmetric hydrogenation over chiral molecule-modified metal particles.catalysis science & technology,5(2),650-659. |
| MLA | Zhan, Ensheng,et al."Heterogeneous asymmetric hydrogenation over chiral molecule-modified metal particles".catalysis science & technology 5.2(2015):650-659. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。