A Porphyrin-Inspired Iron Catalyst for Asymmetric Epoxidation of Electron-Deficient Olefins
文献类型：期刊论文
| 作者 | Dai, Wen1,2; Li, Guosong1,2; Chen, Bo1,2; Wang, Lianyue1,2; Gao, Shuang1,2 |
| 刊名 | organic letters
 |
| 出版日期 | 2015-02-20 |
| 卷号 | 17期号:4页码:904-907 |
| 英文摘要 | an in situ formed porphyrin-inspired iron complex that catalyzes asymmetric epoxidation of di- and trisubstituted enones is described. the reaction provides highly enantioenriched alpha,beta-epoxyketones (up to 99% ee). the practical utility of the new catalyst system is demonstrated by the gram-scale synthesis of optically pure epoxide. hammett analysis suggests that the transition state of the reaction is electron-demanding and the active oxidant is electrophilic. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | highly enantioselective epoxidation ; aqueous hydrogen-peroxide ; wide substrate scope ; alpha,beta-unsaturated ketones ; manganese complex ; beta,beta-disubstituted enones ; stereoselective epoxidation ; unfunctionalized olefins ; oxidation catalysis ; terminal olefins |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000349942600036 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146029]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dai, Wen,Li, Guosong,Chen, Bo,et al. A Porphyrin-Inspired Iron Catalyst for Asymmetric Epoxidation of Electron-Deficient Olefins[J]. organic letters,2015,17(4):904-907. |
| APA | Dai, Wen,Li, Guosong,Chen, Bo,Wang, Lianyue,&Gao, Shuang.(2015).A Porphyrin-Inspired Iron Catalyst for Asymmetric Epoxidation of Electron-Deficient Olefins.organic letters,17(4),904-907. |
| MLA | Dai, Wen,et al."A Porphyrin-Inspired Iron Catalyst for Asymmetric Epoxidation of Electron-Deficient Olefins".organic letters 17.4(2015):904-907. |
入库方式： OAI收割
来源：大连化学物理研究所
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