In-situ P-31 MAS NMR probing of the active centers in Ti silicalite molecular sieve
文献类型：期刊论文
| 作者 | Zhuang, Jianqin1,2; Han, Xiuwen2; Bao, Xinhe2 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2015-03-05 |
| 卷号 | 62页码:75-78 |
| 关键词 | TS-1 zeolite Trimethylphosphine Active center P-31 MAS NMR |
| 英文摘要 | the investigation of the active centers in titanium zeolite was conducted by a probe reaction, the oxidation of trimethylphosphine. the different sites of ts-1 zeolite can be clearly distinguished through p-31 solid-state mas nmr spectra of adsorbed trimethylphosphine. the results showed that only the trimethylphosphine bound to the coordinate-unsaturated framework ti sites and the distorted tetrahedral ti sites ofts-1 zeolite could be easily oxidized by urea hydrogen peroxide. diffuse reflectance uv-vis and si-29 mas nmr spectra further confirmed that the titanium peroxide species (tiooh), which is formed through the solid-solid interaction between urea-h2o2 and ts-1 zeolite, could be catalytic active centers during the oxidation of trimethylphosphine. (c) 2015 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | resonance raman-spectroscopy ; ts-1 zeolite ; catalysts ; acidity ; titanium |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350095100017 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146036]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.CUNY Coll Staten Isl, Dept Chem, Staten Isl, NY 10314 USA 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhuang, Jianqin,Han, Xiuwen,Bao, Xinhe. In-situ P-31 MAS NMR probing of the active centers in Ti silicalite molecular sieve[J]. catalysis communications,2015,62:75-78. |
| APA | Zhuang, Jianqin,Han, Xiuwen,&Bao, Xinhe.(2015).In-situ P-31 MAS NMR probing of the active centers in Ti silicalite molecular sieve.catalysis communications,62,75-78. |
| MLA | Zhuang, Jianqin,et al."In-situ P-31 MAS NMR probing of the active centers in Ti silicalite molecular sieve".catalysis communications 62(2015):75-78. |
入库方式： OAI收割
来源：大连化学物理研究所
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