Abnormal Effects of Cations (Li+, Na+, and K+) on Photoelectrochemical and Electrocatalytic Water Splitting
文献类型：期刊论文
| 作者 | Ding, Chunmei; Zhou, Xin; Shi, Jingying; Yan, Pengli; Wang, Zhiliang; Liu, Guiji; Li, Can |
| 刊名 | journal of physical chemistry b
 |
| 出版日期 | 2015-02-26 |
| 卷号 | 119期号:8页码:3560-3566 |
| 英文摘要 | the electrodeelectrolyte interface chemistry is highly important for photoelectrochemical (pec) and electrocatalytic water splitting where cations in the electrolyte are often crucial. however, the roles of cations in an electrolyte are much debated and not well-understood. this work reports that the pec and electrocatalytic water oxidation (wo) activities in basic electrolytes with different cations follow an unexpected trend (li+ > k+ > na+) especially for long-term reaction. such an abnormal order of activity is found to be the balance effect of two factors: the distinct extents of the weakening of o-h bond on electrode surface after interacting with cations in different electrolytes and the different rates of oxygen reduction reaction (orr) which turns out to be dominant. li+ not only brings the most significant decrease of oh bond strength but also is most effective for avoiding back reaction, while na+ shows the most detrimental effect on wo because of orr. our results provide important insight into the roles of cations in wo and demonstrate a new strategy of tailoring the electrode-electrolyte interface via judicious choice of cations in electrolyte for more efficient pec and electrocatalytic water splitting. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | sensitized solar-cells ; hydrogen-production ; visible-light ; oxidation catalysts ; bismuth vanadate ; photoanodes ; electrodes ; interfaces ; reduction ; evolution |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350329000023 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146038]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding, Chunmei,Zhou, Xin,Shi, Jingying,et al. Abnormal Effects of Cations (Li+, Na+, and K+) on Photoelectrochemical and Electrocatalytic Water Splitting[J]. journal of physical chemistry b,2015,119(8):3560-3566. |
| APA | Ding, Chunmei.,Zhou, Xin.,Shi, Jingying.,Yan, Pengli.,Wang, Zhiliang.,...&Li, Can.(2015).Abnormal Effects of Cations (Li+, Na+, and K+) on Photoelectrochemical and Electrocatalytic Water Splitting.journal of physical chemistry b,119(8),3560-3566. |
| MLA | Ding, Chunmei,et al."Abnormal Effects of Cations (Li+, Na+, and K+) on Photoelectrochemical and Electrocatalytic Water Splitting".journal of physical chemistry b 119.8(2015):3560-3566. |
入库方式： OAI收割
来源：大连化学物理研究所
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