Bronsted Acid Catalyzed PhSe Transfer versus Radical Aryl Transfer: Linear Codimerization of Styrenes and Internal Olefins
文献类型:期刊论文
| 作者 | Wu, Ping1; Wang, Liandi1; Wu, Kaikai1; Yu, Zhengkun1,2 |
| 刊名 | organic letters
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| 出版日期 | 2015-02-20 |
| 卷号 | 17期号:4页码:868-871 |
| 英文摘要 | bronsted acid p-(tsohh2o)-h-.-catalyzed hydrovinylation of styrenes with internal olefins alpha-oxo ketene dithioacetals was efficiently achieved in the presence of n-phenylselenophthalimide (n-psp), regioselectively affording markovnikov phenylselenative hydrovinylation products through phse transfer of the phenylseleno ketene dithioacetal intermediates. radical reduction of the resultant phse-alkyl-substituted ketene dithioacetals with aibn/n-bu3snh gave the corresponding anti-markovnikov hydrovinylation products formally from the linear codimerization of styrenes and the internal olefins. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | oxo ketene dithioacetals ; asymmetric hydrovinylation ; efficient synthesis ; addition-reactions ; ruthenium-complex ; bond activation ; iridium complex ; alkenes ; dimerization ; carbon |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000349942600027 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146041] ![]() |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Ping,Wang, Liandi,Wu, Kaikai,et al. Bronsted Acid Catalyzed PhSe Transfer versus Radical Aryl Transfer: Linear Codimerization of Styrenes and Internal Olefins[J]. organic letters,2015,17(4):868-871. |
| APA | Wu, Ping,Wang, Liandi,Wu, Kaikai,&Yu, Zhengkun.(2015).Bronsted Acid Catalyzed PhSe Transfer versus Radical Aryl Transfer: Linear Codimerization of Styrenes and Internal Olefins.organic letters,17(4),868-871. |
| MLA | Wu, Ping,et al."Bronsted Acid Catalyzed PhSe Transfer versus Radical Aryl Transfer: Linear Codimerization of Styrenes and Internal Olefins".organic letters 17.4(2015):868-871. |
入库方式: OAI收割
来源:大连化学物理研究所
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