Interface Engineering of a CoOx/Ta3N5 Photocatalyst for Unprecedented Water Oxidation Performance under Visible-Light-Irradiation
文献类型：期刊论文
| 作者 | Chen, Shanshan1,2; Shen, Shuai1; Liu, Guiji1,2; Qi, Yu1,2; Zhang, Fuxiang1; Li, Can1 |
| 刊名 | angewandte chemie-international edition
 |
| 出版日期 | 2015-03-02 |
| 卷号 | 54期号:10页码:3047-3051 |
| 关键词 | cocatalysts interface engineering photocatalysis tantalum nitride water splitting |
| 英文摘要 | cocatalysts have been extensively used to promote water oxidation efficiency in solar-to-chemical energy conversion, but the influence of interface compatibility between semiconductor and cocatalyst has been rarely addressed. here we demonstrate a feasible strategy of interface wettability modification to enhance water oxidation efficiency of the state-of-the-art coox/ta3n5 system. when the hydrophobic feature of a ta3n5 semiconductor was modulated to a hydrophilic one by insitu or exsitu surface coating with a magnesia nanolayer (2-5nm), the interfacial contact between the hydrophilic coox cocatalyst and the modified hydrophilic ta3n5 semiconductor was greatly improved. consequently, the visible-light-driven photocatalytic oxygen evolution rate of the resulting coox/mgo(in)-ta3n5 photocatalyst is ca. 23 times that of the pristine ta3n5 sample, with a new record (11.3%) of apparent quantum efficiency (aqe) under 500-600nm illumination. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | ta-o-n ; recent progress ; core/shell nanoparticles ; layer ; photoanodes ; bivo4 ; fabrication ; cocatalyst ; catalysts ; natao3 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350302300030 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146059]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Shanshan,Shen, Shuai,Liu, Guiji,et al. Interface Engineering of a CoOx/Ta3N5 Photocatalyst for Unprecedented Water Oxidation Performance under Visible-Light-Irradiation[J]. angewandte chemie-international edition,2015,54(10):3047-3051. |
| APA | Chen, Shanshan,Shen, Shuai,Liu, Guiji,Qi, Yu,Zhang, Fuxiang,&Li, Can.(2015).Interface Engineering of a CoOx/Ta3N5 Photocatalyst for Unprecedented Water Oxidation Performance under Visible-Light-Irradiation.angewandte chemie-international edition,54(10),3047-3051. |
| MLA | Chen, Shanshan,et al."Interface Engineering of a CoOx/Ta3N5 Photocatalyst for Unprecedented Water Oxidation Performance under Visible-Light-Irradiation".angewandte chemie-international edition 54.10(2015):3047-3051. |
入库方式： OAI收割
来源：大连化学物理研究所
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