Sensitive simultaneous determination of nitrophenol isomers at poly (p-aminobenzene sulfonic acid) film modified graphite electrode
文献类型：期刊论文
| 作者 | Yao, Chuan1; Sun, Hong1; Fu, Hua-Feng1; Tan, Zhi-Cheng2 |
| 刊名 | electrochimica acta
 |
| 出版日期 | 2015-02-20 |
| 卷号 | 156页码:163-170 |
| 关键词 | p-Aminobenzene sulfonic acid Modified electrode Nitrophenol isomers Simultaneous determination Semi-derivative voltammetry |
| 英文摘要 | poly(p-aminobenzene sulfonic acid)-modified graphite electrode [poly(p-absa)/ge] was prepared via a straightforward one-step electropolymerization and was employed to investigate the electrochemical behavior of o-nitrophenol (o-np), m-nitrophenol (m-np) and p-nitrophenol (p-np), for the purpose of realizing the simultaneous determination of nitrophenol isomers. semi-derivative voltammetry (sdv) was adopted to enhance the resolution and sensitivity. compared with the bare ge, poly(p-absa)/ge exhibited excellent electrocatalytic activity towards the oxidation process of the intermediate products of nitrophenol isomers. thus, o-, m- and p-np can be clearly identified and successfully separated at 0.119v, -0.125v and 0.027v (vs. saturated calomel electrode). under the optimized experimental conditions, the linear ranges of the calibration curves were 3 similar to 800 mu mol l-1 for o-np, and 3 similar to 700 mu mol l-1 for both m-np and p-np. in addition, the low detection limits for o-, m- and p-np were 0.28, 0.5 and 0.3 mu mol l-1, respectively (s/n = 3). the proposed method is novel and has many advantages such as simple, sensitive, selective, reproducible and cost-effective. therefore, it can be considered a promising sensing platform for direct simultaneous determination of nitrophenol isomers in water samples. (c) 2015 published by elsevier ltd. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | electrochemistry |
| 研究领域[WOS] | electrochemistry |
| 关键词[WOS] | glassy-carbon electrode ; voltammetric determination ; electrochemical detection ; liquid-chromatography ; pulse voltammetry ; graphene oxide ; ascorbic-acid ; ece mechanism ; sensor ; 4-nitrophenol |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350444600021 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146062]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Xuchang Univ, Sch Chem & Chem Engn, Xuchang 461000, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, Chuan,Sun, Hong,Fu, Hua-Feng,et al. Sensitive simultaneous determination of nitrophenol isomers at poly (p-aminobenzene sulfonic acid) film modified graphite electrode[J]. electrochimica acta,2015,156:163-170. |
| APA | Yao, Chuan,Sun, Hong,Fu, Hua-Feng,&Tan, Zhi-Cheng.(2015).Sensitive simultaneous determination of nitrophenol isomers at poly (p-aminobenzene sulfonic acid) film modified graphite electrode.electrochimica acta,156,163-170. |
| MLA | Yao, Chuan,et al."Sensitive simultaneous determination of nitrophenol isomers at poly (p-aminobenzene sulfonic acid) film modified graphite electrode".electrochimica acta 156(2015):163-170. |
入库方式： OAI收割
来源：大连化学物理研究所
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