Promotion effect of Fe in mordenite zeolite on carbonylation of dimethyl ether to methyl acetate
文献类型：期刊论文
| 作者 | Zhou, Hui1,2,3; Zhu, Wenliang1,2; Shi, Lei1,2; Liu, Hongchao1,2; Liu, Shiping1,2,3; Xu, Shutao1,2; Ni, Youming1,2; Liu, Yong1,2; Li, Lina1,2,3; Liu, Zhongmin1,2 |
| 刊名 | catalysis science & technology
 |
| 出版日期 | 2015-03-01 |
| 卷号 | 5期号:3页码:1961-1968 |
| 英文摘要 | a series of fe-modified mordenite zeolite samples were synthesized by a template-free method and employed in dimethyl ether (dme) carbonylation reaction for the production of methyl acetate (mac). xrd, uv-vis, and uv-raman characterization studies proved that fe atoms have been introduced into the mordenite zeolite framework by partial substitution of al atoms, which led to evident changes of activity and mac selectivity. with the increase of iron content (as metal) from 0.0 to 3.6 wt%, dme conversion first increased and then decreased. mac selectivity and catalyst stability were enhanced for all fe-modified samples. tg and gc-ms analysis of deactivated catalysts showed that the amount of coke retained in the catalysts decreased as the iron content of the zeolites increased. the enhancement effects were expounded in terms of the decrease of the acid strength and acid density in the 12mr channels of mordenite after introduction of fe, resulting in the reduction of carbon deposition. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | solid acid catalysts ; resonance raman-spectroscopy ; selective carbonylation ; n2o decomposition ; p-31 nmr ; methanol ; iron ; framework ; ethanol ; enhancement |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350685400065 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146081]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Hui,Zhu, Wenliang,Shi, Lei,et al. Promotion effect of Fe in mordenite zeolite on carbonylation of dimethyl ether to methyl acetate[J]. catalysis science & technology,2015,5(3):1961-1968. |
| APA | Zhou, Hui.,Zhu, Wenliang.,Shi, Lei.,Liu, Hongchao.,Liu, Shiping.,...&Liu, Zhongmin.(2015).Promotion effect of Fe in mordenite zeolite on carbonylation of dimethyl ether to methyl acetate.catalysis science & technology,5(3),1961-1968. |
| MLA | Zhou, Hui,et al."Promotion effect of Fe in mordenite zeolite on carbonylation of dimethyl ether to methyl acetate".catalysis science & technology 5.3(2015):1961-1968. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。