Cerium-Oxide-Modified Nickel as a Non-Noble Metal Catalyst for Selective Decomposition of Hydrous Hydrazine to Hydrogen
文献类型：期刊论文
| 作者 | He, Lei1,2; Liang, Binglian1,2; Li, Lin1; Yang, Xiaofeng1; Huang, Yanqiang1; Wang, Aiqin1; Wang, Xiaodong1; Zhang, Tao1 |
| 刊名 | acs catalysis
 |
| 出版日期 | 2015-03-01 |
| 卷号 | 5期号:3页码:1623-1628 |
| 关键词 | hydrogen generation hydrous hydrazine non-noble metal Ni-CeO2 Ni-O-Ce |
| 英文摘要 | hydrous hydrazine is identified as a hydrogen reservoir owing to its high content of hydrogen (8.0 wt %). its selective decomposition under mild conditions is the key for quick h-2 release. modifying ni nanoparticles with a small amount of ceo2 (8.0 mol %) resulted in a 3-fold increase of turnover frequency (tof) and an enhancement of h-2 selectivity from 67% to above 99%. this improvement was due to the modification of ni with ceo2 nearby through strong metal-support interaction (e.g., ni-o-ce structure). furthermore, this promoting effect was extended to other oxides which can form strong metal-support interaction with ni, such as zro2, mgo, and la2o3. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | highly efficient catalyst ; room-temperature ; h-2 production ; ambient conditions ; co oxidation ; generation ; ni ; storage ; nanoparticles ; support |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350843500028 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146084]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Lei,Liang, Binglian,Li, Lin,et al. Cerium-Oxide-Modified Nickel as a Non-Noble Metal Catalyst for Selective Decomposition of Hydrous Hydrazine to Hydrogen[J]. acs catalysis,2015,5(3):1623-1628. |
| APA | He, Lei.,Liang, Binglian.,Li, Lin.,Yang, Xiaofeng.,Huang, Yanqiang.,...&Zhang, Tao.(2015).Cerium-Oxide-Modified Nickel as a Non-Noble Metal Catalyst for Selective Decomposition of Hydrous Hydrazine to Hydrogen.acs catalysis,5(3),1623-1628. |
| MLA | He, Lei,et al."Cerium-Oxide-Modified Nickel as a Non-Noble Metal Catalyst for Selective Decomposition of Hydrous Hydrazine to Hydrogen".acs catalysis 5.3(2015):1623-1628. |
入库方式： OAI收割
来源：大连化学物理研究所
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